Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4
Patrick Bonnick
1
,
Lauren Blanc
1
,
Shahrzad Hosseini Vajargah
1
,
Chang Wook Lee
2
,
Xiaoqi Sun
1
,
Publication type: Journal Article
Publication date: 2018-06-22
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The Mg battery cathode material, thiospinel MgxZr2S4 (0 ≤ x ≤ 1), exhibits negligible volume change (ca. 0.05%) during electrochemical cycling, providing valuable insight into the limiting factors in divalent cation intercalation. Rietveld refinement of XRD data for MgxZr2S4 electrodes at various states of charge, , coupled with EDX analysis, demonstrates that Mg2+ can be inserted into Zr2S4 at 60 °C up to x = 0.7 at a C/10 rate (up to x = 0.9 at very slow rates) and cycled with a high Coulombic efficiency of 99.75%. HAADF-STEM studies provide clear visual evidence of Mg-ion occupation in the lattice, whereas XAS studies show that Zr4+ was reduced upon Mg2+ intercalation. Operando and synchrotron XRD studies reveal the creation of two phases during the latter stages of discharge (x > 0.5) as the lattice fills and Mg2+ ions begin occupying tetrahedral (8a) sites in addition to octahedral (16c) interstitial sites. Compared to the isostructural Ti2S4 thiospinel, Zr2S4 presents a slightly larger cell volume a...
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46
Total citations:
46
Citations from 2024:
12
(26.09%)
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Bonnick P. et al. Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4 // Chemistry of Materials. 2018. Vol. 30. No. 14. pp. 4683-4693.
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Bonnick P., Blanc L., Vajargah S. H., Lee C. W., Sun X., Balasubramanian M., Nazar L. F. Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4 // Chemistry of Materials. 2018. Vol. 30. No. 14. pp. 4683-4693.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.8b01345
UR - https://doi.org/10.1021/acs.chemmater.8b01345
TI - Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4
T2 - Chemistry of Materials
AU - Bonnick, Patrick
AU - Blanc, Lauren
AU - Vajargah, Shahrzad Hosseini
AU - Lee, Chang Wook
AU - Sun, Xiaoqi
AU - Balasubramanian, Mahalingam
AU - Nazar, Linda F.
PY - 2018
DA - 2018/06/22
PB - American Chemical Society (ACS)
SP - 4683-4693
IS - 14
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2018_Bonnick,
author = {Patrick Bonnick and Lauren Blanc and Shahrzad Hosseini Vajargah and Chang Wook Lee and Xiaoqi Sun and Mahalingam Balasubramanian and Linda F. Nazar},
title = {Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.chemmater.8b01345},
number = {14},
pages = {4683--4693},
doi = {10.1021/acs.chemmater.8b01345}
}
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Bonnick, Patrick, et al. “Insights into Mg2+ Intercalation in a Zero-Strain Material: Thiospinel MgxZr2S4.” Chemistry of Materials, vol. 30, no. 14, Jun. 2018, pp. 4683-4693. https://doi.org/10.1021/acs.chemmater.8b01345.
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