Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium
Sergey Fateev
1
,
Sergey A Fateev
1
,
Andrey A. Petrov
1
,
Victor N. Khrustalev
2, 3
,
Eugene Goodilin
1, 4
,
Eugene A. Goodilin
1, 4
,
Alexey Tarasov
1, 4
Publication type: Journal Article
Publication date: 2018-07-17
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The chemical origin of solvents typically used for preparation of hybrid lead halide perovskites—dimethyl sulfoxide (DMSO), dimethylformamide (DMF), and γ-butyrolactone (GBL)—strongly influences the process of perovskite crystallization because of the formation of intermediate adducts with different structures and morphology. The composition and crystal structures of the adducts depend on the coordination and binding ability of the solvents and the ratio of the precursors. New adducts of perovskite and GBL with either an unusual cluster structure, (MA)8(GBL)x[Pb18I44], or an adduct, (MA)2(GBL)2Pb3I8, similar to those observed for DMF and DMSO are described for the first time. Complex equilibriums between chemical species existing in perovskite solutions are revealed by Raman spectroscopy. As a result, new features of the perovskite crystallization through intermediate adduct phases are discussed, and effective perovskite deposition pathways are suggested.
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Fateev S. et al. Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium // Chemistry of Materials. 2018. Vol. 30. No. 15. pp. 5237-5244.
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Fateev S., Fateev S. A., Petrov A. A., Khrustalev V. N., Dorovatovskii P., Zubavichus Y. V., Goodilin E., Goodilin E. A., Tarasov A. Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium // Chemistry of Materials. 2018. Vol. 30. No. 15. pp. 5237-5244.
Cite this
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TY - JOUR
DO - 10.1021/acs.chemmater.8b01906
UR - https://pubs.acs.org/doi/10.1021/acs.chemmater.8b01906
TI - Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium
T2 - Chemistry of Materials
AU - Fateev, Sergey
AU - Fateev, Sergey A
AU - Petrov, Andrey A.
AU - Khrustalev, Victor N.
AU - Dorovatovskii, Pavel
AU - Zubavichus, Yan V.
AU - Goodilin, Eugene
AU - Goodilin, Eugene A.
AU - Tarasov, Alexey
PY - 2018
DA - 2018/07/17
PB - American Chemical Society (ACS)
SP - 5237-5244
IS - 15
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2018_Fateev,
author = {Sergey Fateev and Sergey A Fateev and Andrey A. Petrov and Victor N. Khrustalev and Pavel Dorovatovskii and Yan V. Zubavichus and Eugene Goodilin and Eugene A. Goodilin and Alexey Tarasov},
title = {Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.chemmater.8b01906},
number = {15},
pages = {5237--5244},
doi = {10.1021/acs.chemmater.8b01906}
}
Cite this
MLA
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Fateev, Sergey, et al. “Solution Processing of Methylammonium Lead Iodide Perovskite from γ-Butyrolactone: Crystallization Mediated by Solvation Equilibrium.” Chemistry of Materials, vol. 30, no. 15, Jul. 2018, pp. 5237-5244. https://pubs.acs.org/doi/10.1021/acs.chemmater.8b01906.