Chemistry of Materials, volume 30, issue 14, pages 4831-4837

Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder

Publication typeJournal Article
Publication date2018-07-03
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.6
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Nanocrystal (NC) solids are commonly prepared from nonpolar organic NC suspensions. In many cases, the capping on the NC surface is preserved and forms a barrier between the NCs. More recently, superstructures with crystalline connections between the NCs, implying the removal of the capping, have been reported, too. Here, we present large-scale uniform superstructures of attached PbSe NCs with a silicene-type honeycomb geometry, resulting from solvent evaporation under nearly reversible conditions. We also prepared multilayered silicene honeycomb structures by using larger amounts of PbSe NCs. We show that the two-dimensional silicene superstructures can be seen as a crystallographic slice from a 3-D simple cubic structure. We describe the disorder in the silicene lattices in terms of the nanocrystals position and their atomic alignment. The silicene honeycomb sheets are large enough to be used in transistors and optoelectronic devices.

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Peters A. L. et al. Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder // Chemistry of Materials. 2018. Vol. 30. No. 14. pp. 4831-4837.
GOST all authors (up to 50) Copy
Peters A. L., Altantzis T., Lobato I., Jazi M. A., Van Overbeek C., Bals S., Vanmaekelbergh D., Sinai S. B. Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder // Chemistry of Materials. 2018. Vol. 30. No. 14. pp. 4831-4837.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b02178
UR - https://doi.org/10.1021/acs.chemmater.8b02178
TI - Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder
T2 - Chemistry of Materials
AU - Altantzis, Thomas
AU - Lobato, Ivan
AU - Jazi, Maryam Alimoradi
AU - Sinai, Sophia Buhbut
AU - Peters, Anna L
AU - Van Overbeek, Carlo
AU - Bals, Sara
AU - Vanmaekelbergh, Daniel
PY - 2018
DA - 2018/07/03 00:00:00
PB - American Chemical Society (ACS)
SP - 4831-4837
IS - 14
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
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BibTex Copy
@article{2018_Peters,
author = {Thomas Altantzis and Ivan Lobato and Maryam Alimoradi Jazi and Sophia Buhbut Sinai and Anna L Peters and Carlo Van Overbeek and Sara Bals and Daniel Vanmaekelbergh},
title = {Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.chemmater.8b02178},
number = {14},
pages = {4831--4837},
doi = {10.1021/acs.chemmater.8b02178}
}
MLA
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MLA Copy
Peters, Anna L., et al. “Mono- and Multilayer Silicene-Type Honeycomb Lattices by Oriented Attachment of PbSe Nanocrystals: Synthesis, Structural Characterization, and Analysis of the Disorder.” Chemistry of Materials, vol. 30, no. 14, Jul. 2018, pp. 4831-4837. https://doi.org/10.1021/acs.chemmater.8b02178.
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