Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies
Bernhard T. Leube
1
,
Kenneth K Inglis
1
,
Elliot C. Carrington
1
,
Paul M. Sharp
1
,
J Felix Shin
1
,
Alex R. Neale
1, 2
,
Troy D. Manning
1
,
Laurence J. Hardwick
1, 2
,
Matthew Dyer
1
,
Frédéric Blanc
1, 2
,
John B. Claridge
1
,
Publication type: Journal Article
Publication date: 2018-09-13
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
To understand the structural and compositional factors controlling lithium transport in sulfides, we explored the Li5AlS4–Li4GeS4 phase field for new materials. Both parent compounds are defined structurally by a hexagonal close packed sulfide lattice, where distinct arrangements of tetrahedral metal sites give Li5AlS4 a layered structure and Li4GeS4 a three-dimensional structure related to γ-Li3PO4. The combination of the two distinct structural motifs is expected to lead to new structural chemistry. We identified the new crystalline phase Li4.4Al0.4Ge0.6S4, and investigated the structure and Li+ ion dynamics of the family of structurally related materials Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+ and M′ = Ge4+, Sn4+). We used neutron diffraction to solve the full structures of the Al-homologues, which adopt a layered close-packed structure with a new arrangement of tetrahedral (M/M′) sites and a novel combination of ordered and disordered lithium vacancies. AC impedance spectroscopy revealed lithium conductiviti...
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
8
9
|
|
|
Chemistry of Materials
9 publications, 26.47%
|
|
|
ACS Applied Energy Materials
2 publications, 5.88%
|
|
|
Journal of the American Chemical Society
2 publications, 5.88%
|
|
|
Dalton Transactions
2 publications, 5.88%
|
|
|
ACS applied materials & interfaces
1 publication, 2.94%
|
|
|
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
1 publication, 2.94%
|
|
|
Functional Materials Letters
1 publication, 2.94%
|
|
|
Nature Communications
1 publication, 2.94%
|
|
|
npj Computational Materials
1 publication, 2.94%
|
|
|
Progress in Energy
1 publication, 2.94%
|
|
|
Advanced Materials
1 publication, 2.94%
|
|
|
Nano Letters
1 publication, 2.94%
|
|
|
Physical Chemistry Chemical Physics
1 publication, 2.94%
|
|
|
RSC Advances
1 publication, 2.94%
|
|
|
Annual Reports on NMR Spectroscopy
1 publication, 2.94%
|
|
|
Energy Storage Materials
1 publication, 2.94%
|
|
|
Solid State Ionics
1 publication, 2.94%
|
|
|
Nano Energy
1 publication, 2.94%
|
|
|
Materials Today Energy
1 publication, 2.94%
|
|
|
1
2
3
4
5
6
7
8
9
|
Publishers
|
2
4
6
8
10
12
14
16
|
|
|
American Chemical Society (ACS)
15 publications, 44.12%
|
|
|
Elsevier
7 publications, 20.59%
|
|
|
Royal Society of Chemistry (RSC)
4 publications, 11.76%
|
|
|
Springer Nature
2 publications, 5.88%
|
|
|
The Royal Society
1 publication, 2.94%
|
|
|
World Scientific
1 publication, 2.94%
|
|
|
IOP Publishing
1 publication, 2.94%
|
|
|
Wiley
1 publication, 2.94%
|
|
|
2
4
6
8
10
12
14
16
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
34
Total citations:
34
Citations from 2024:
6
(17%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Leube B. T. et al. Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7183-7200.
GOST all authors (up to 50)
Copy
Leube B. T., Inglis K. K., Carrington E. C., Sharp P. M., Shin J. F., Neale A. R., Manning T. D., Pitcher M. J., Hardwick L. J., Dyer M., Blanc F., Claridge J. B., Rosseinsky M. J. Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7183-7200.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b03175
UR - https://doi.org/10.1021/acs.chemmater.8b03175
TI - Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies
T2 - Chemistry of Materials
AU - Leube, Bernhard T.
AU - Inglis, Kenneth K
AU - Carrington, Elliot C.
AU - Sharp, Paul M.
AU - Shin, J Felix
AU - Neale, Alex R.
AU - Manning, Troy D.
AU - Pitcher, Michael J.
AU - Hardwick, Laurence J.
AU - Dyer, Matthew
AU - Blanc, Frédéric
AU - Claridge, John B.
AU - Rosseinsky, Matthew J.
PY - 2018
DA - 2018/09/13
PB - American Chemical Society (ACS)
SP - 7183-7200
IS - 20
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Leube,
author = {Bernhard T. Leube and Kenneth K Inglis and Elliot C. Carrington and Paul M. Sharp and J Felix Shin and Alex R. Neale and Troy D. Manning and Michael J. Pitcher and Laurence J. Hardwick and Matthew Dyer and Frédéric Blanc and John B. Claridge and Matthew J. Rosseinsky},
title = {Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.chemmater.8b03175},
number = {20},
pages = {7183--7200},
doi = {10.1021/acs.chemmater.8b03175}
}
Cite this
MLA
Copy
Leube, Bernhard T., et al. “Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies.” Chemistry of Materials, vol. 30, no. 20, Sep. 2018, pp. 7183-7200. https://doi.org/10.1021/acs.chemmater.8b03175.