Chemistry of Materials

, том 30 , издание 20 , страницы 7183-7200

Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies

Bernhard T. Leube ¹

Kenneth K Inglis ¹

Elliot C. Carrington ¹

Paul M. Sharp ¹

J Felix Shin ¹

Alex R. Neale ^{1, 2}

Troy D. Manning ¹

Michael J. Pitcher ¹

Laurence J. Hardwick ^{1, 2}

Matthew Dyer ¹

Frédéric Blanc ^{1, 2}

John B. Claridge ¹

Matthew J. Rosseinsky ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 2 аффилиации

Department of Chemistry, University of Liverpool, Crown Street, L69 7ZD Liverpool, U.K. |

Stephenson Institute for Renewable Energy, University of Liverpool, Peach Street, L69 7ZF Liverpool, U.K. |

Тип публикации: Journal Article

Дата публикации: 2018-09-13

American Chemical Society (ACS)

Chemistry of Materials

scimago Q1

wos Q1

БС1

SJR: 2.065

CiteScore: 12.0

Impact factor: 7.0

ISSN: 08974756, 15205002

DOI: 10.1021/acs.chemmater.8b03175

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Materials Chemistry

General Chemistry

General Chemical Engineering

Краткое описание

To understand the structural and compositional factors controlling lithium transport in sulfides, we explored the Li5AlS4–Li4GeS4 phase field for new materials. Both parent compounds are defined structurally by a hexagonal close packed sulfide lattice, where distinct arrangements of tetrahedral metal sites give Li5AlS4 a layered structure and Li4GeS4 a three-dimensional structure related to γ-Li3PO4. The combination of the two distinct structural motifs is expected to lead to new structural chemistry. We identified the new crystalline phase Li4.4Al0.4Ge0.6S4, and investigated the structure and Li+ ion dynamics of the family of structurally related materials Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+ and M′ = Ge4+, Sn4+). We used neutron diffraction to solve the full structures of the Al-homologues, which adopt a layered close-packed structure with a new arrangement of tetrahedral (M/M′) sites and a novel combination of ordered and disordered lithium vacancies. AC impedance spectroscopy revealed lithium conductiviti...

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Leube B. T. et al. Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7183-7200.

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Leube B. T., Inglis K. K., Carrington E. C., Sharp P. M., Shin J. F., Neale A. R., Manning T. D., Pitcher M. J., Hardwick L. J., Dyer M., Blanc F., Claridge J. B., Rosseinsky M. J. Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies // Chemistry of Materials. 2018. Vol. 30. No. 20. pp. 7183-7200.

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TY - JOUR

DO - 10.1021/acs.chemmater.8b03175

UR - https://doi.org/10.1021/acs.chemmater.8b03175

TI - Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies

T2 - Chemistry of Materials

AU - Leube, Bernhard T.

AU - Inglis, Kenneth K

AU - Carrington, Elliot C.

AU - Sharp, Paul M.

AU - Shin, J Felix

AU - Neale, Alex R.

AU - Manning, Troy D.

AU - Pitcher, Michael J.

AU - Hardwick, Laurence J.

AU - Dyer, Matthew

AU - Blanc, Frédéric

AU - Claridge, John B.

AU - Rosseinsky, Matthew J.

PY - 2018

DA - 2018/09/13

PB - American Chemical Society (ACS)

SP - 7183-7200

IS - 20

VL - 30

SN - 0897-4756

SN - 1520-5002

ER -

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@article{2018_Leube,

author = {Bernhard T. Leube and Kenneth K Inglis and Elliot C. Carrington and Paul M. Sharp and J Felix Shin and Alex R. Neale and Troy D. Manning and Michael J. Pitcher and Laurence J. Hardwick and Matthew Dyer and Frédéric Blanc and John B. Claridge and Matthew J. Rosseinsky},

title = {Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies},

journal = {Chemistry of Materials},

year = {2018},

volume = {30},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021/acs.chemmater.8b03175},

number = {20},

pages = {7183--7200},

doi = {10.1021/acs.chemmater.8b03175}

}

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Leube, Bernhard T., et al. “Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies.” Chemistry of Materials, vol. 30, no. 20, Sep. 2018, pp. 7183-7200. https://doi.org/10.1021/acs.chemmater.8b03175.

Издатель

American Chemical Society (ACS)

Журнал

Chemistry of Materials

scimago Q1

wos Q1

БС1

SJR

2.065

CiteScore

12.0

Impact factor

7.0

ISSN

08974756 (Print)

15205002 (Electronic)

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