volume 30 issue 18 pages 6559-6565

The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction

Ryan A Dodson
Antek G. Wong-Foy
Publication typeJournal Article
Publication date2018-09-04
scimago Q1
wos Q1
SJR2.065
CiteScore12.0
Impact factor7.0
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The process of activation, an essential step to reveal the porosity of metal–organic frameworks (MOFs), was examined for materials that produce surface areas in accord with prediction as well as for those failing to meet expectations. In situ two-dimensional powder X-ray diffraction, in combination with surface area measurements, was used to classify the structural outcomes of a variety of MOF activations. By modulation of activation solvent as well as linker length and flexibility, a variety of structural outcomes were obtained. In addition to pristine and amorphous products, MOFs that exhibit intermediate activation success were observed. Such MOFs were found to undergo reductions in crystallite size while varying in total amorphous content, which leads to vastly different product surface areas. Models to explain different activation outcomes are presented.
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GOST Copy
Dodson R. A., Wong-Foy A. G., Matzger A. J. The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction // Chemistry of Materials. 2018. Vol. 30. No. 18. pp. 6559-6565.
GOST all authors (up to 50) Copy
Dodson R. A., Wong-Foy A. G., Matzger A. J. The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction // Chemistry of Materials. 2018. Vol. 30. No. 18. pp. 6559-6565.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b03378
UR - https://doi.org/10.1021/acs.chemmater.8b03378
TI - The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction
T2 - Chemistry of Materials
AU - Dodson, Ryan A
AU - Wong-Foy, Antek G.
AU - Matzger, Adam J.
PY - 2018
DA - 2018/09/04
PB - American Chemical Society (ACS)
SP - 6559-6565
IS - 18
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Dodson,
author = {Ryan A Dodson and Antek G. Wong-Foy and Adam J. Matzger},
title = {The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.chemmater.8b03378},
number = {18},
pages = {6559--6565},
doi = {10.1021/acs.chemmater.8b03378}
}
MLA
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MLA Copy
Dodson, Ryan A., et al. “The Metal–Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction.” Chemistry of Materials, vol. 30, no. 18, Sep. 2018, pp. 6559-6565. https://doi.org/10.1021/acs.chemmater.8b03378.
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