Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides
Dawei Wang
1
,
Xin Chao
2
,
Jiaxin Zheng,
2
,
Ronghui Kou
3
,
Jun Young Peter Ko
4
,
Ashfia Huq
5
,
Guiming Zhong
1
,
Chengjun Sun
3
,
Yong Yang
1
,
Zonghai Chen
6
,
Yinguo Xiao
2
,
Khalil Amine
6
,
Feng Pan
2
4
Publication type: Journal Article
Publication date: 2019-03-07
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Nickel-rich transition-metal (TM) layered oxides, particularly those with high Ni content, attract worldwide interest for potential use as high-capacity cathodes in next-generation Li-ion batteries. However, as Ni loading increases, Li and Ni sitting at octahedra tend to mix, resulting in reduced electrochemical activity, which has been one major obstacle to their practical applications. Herein, we investigate the kinetic and thermodynamic aspects of Li/Ni mixing in LiNi0.7MnxCo0.3–xO2 (0 ≤ x ≤ 0.3) as they are synthesized, through quantitative determination of structural ordering and comparison to ab initio calculations. Results from this study elucidate the role of Co/Mn-substitution in tuning Li/Ni ordering, intrinsically through local magnetic interaction. Specifically, Co substitution facilitates Li/Ni ordering by relieving the intra-plane magnetic frustration and reducing the inter-plane super-exchange (SE) interaction; in contrast, Mn exacerbates magnetic frustration and strengthens SE, thereby agg...
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
16
|
|
|
Advanced Energy Materials
15 publications, 10.87%
|
|
|
Nano Energy
8 publications, 5.8%
|
|
|
Chemical Engineering Journal
8 publications, 5.8%
|
|
|
ACS applied materials & interfaces
8 publications, 5.8%
|
|
|
Energy Storage Materials
5 publications, 3.62%
|
|
|
Advanced Materials
5 publications, 3.62%
|
|
|
Journal of Power Sources
4 publications, 2.9%
|
|
|
Chemistry of Materials
3 publications, 2.17%
|
|
|
Journal of the Electrochemical Society
3 publications, 2.17%
|
|
|
Journal of Materials Chemistry A
3 publications, 2.17%
|
|
|
Nano Research
3 publications, 2.17%
|
|
|
Journal of Alloys and Compounds
3 publications, 2.17%
|
|
|
Journal of Energy Chemistry
3 publications, 2.17%
|
|
|
Journal of Energy Storage
3 publications, 2.17%
|
|
|
Materials Today Energy
3 publications, 2.17%
|
|
|
ACS Energy Letters
3 publications, 2.17%
|
|
|
ACS Applied Energy Materials
3 publications, 2.17%
|
|
|
Electrochimica Acta
3 publications, 2.17%
|
|
|
Batteries & Supercaps
3 publications, 2.17%
|
|
|
Journal of Electroanalytical Chemistry
2 publications, 1.45%
|
|
|
Ceramics International
2 publications, 1.45%
|
|
|
Journal of Colloid and Interface Science
2 publications, 1.45%
|
|
|
Small
2 publications, 1.45%
|
|
|
Advanced Functional Materials
2 publications, 1.45%
|
|
|
Journal of the American Chemical Society
2 publications, 1.45%
|
|
|
Journal of Physical Chemistry C
2 publications, 1.45%
|
|
|
Nano Letters
2 publications, 1.45%
|
|
|
Physical Chemistry Chemical Physics
2 publications, 1.45%
|
|
|
Nature Communications
2 publications, 1.45%
|
|
|
Crystals
1 publication, 0.72%
|
|
|
2
4
6
8
10
12
14
16
|
Publishers
|
10
20
30
40
50
60
|
|
|
Elsevier
56 publications, 40.58%
|
|
|
Wiley
33 publications, 23.91%
|
|
|
American Chemical Society (ACS)
25 publications, 18.12%
|
|
|
Springer Nature
9 publications, 6.52%
|
|
|
Royal Society of Chemistry (RSC)
8 publications, 5.8%
|
|
|
The Electrochemical Society
3 publications, 2.17%
|
|
|
MDPI
2 publications, 1.45%
|
|
|
American Physical Society (APS)
1 publication, 0.72%
|
|
|
OAE Publishing Inc.
1 publication, 0.72%
|
|
|
10
20
30
40
50
60
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
139
Total citations:
139
Citations from 2025:
32
(23.19%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Wang D. et al. Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides // Chemistry of Materials. 2019. Vol. 31. No. 8. pp. 2731-2740.
GOST all authors (up to 50)
Copy
Wang D., Chao X., Zheng, J., Kou R., Peter Ko J. Y., Huq A., Zhong G., Sun C., Yang Y., Chen Z., Xiao Y., Amine K., Pan F. Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides // Chemistry of Materials. 2019. Vol. 31. No. 8. pp. 2731-2740.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b04673
UR - https://doi.org/10.1021/acs.chemmater.8b04673
TI - Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides
T2 - Chemistry of Materials
AU - Wang, Dawei
AU - Chao, Xin
AU - Zheng,, Jiaxin
AU - Kou, Ronghui
AU - Peter Ko, Jun Young
AU - Huq, Ashfia
AU - Zhong, Guiming
AU - Sun, Chengjun
AU - Yang, Yong
AU - Chen, Zonghai
AU - Xiao, Yinguo
AU - Amine, Khalil
AU - Pan, Feng
PY - 2019
DA - 2019/03/07
PB - American Chemical Society (ACS)
SP - 2731-2740
IS - 8
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Wang,
author = {Dawei Wang and Xin Chao and Jiaxin Zheng, and Ronghui Kou and Jun Young Peter Ko and Ashfia Huq and Guiming Zhong and Chengjun Sun and Yong Yang and Zonghai Chen and Yinguo Xiao and Khalil Amine and Feng Pan},
title = {Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.chemmater.8b04673},
number = {8},
pages = {2731--2740},
doi = {10.1021/acs.chemmater.8b04673}
}
Cite this
MLA
Copy
Wang, Dawei, et al. “Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides.” Chemistry of Materials, vol. 31, no. 8, Mar. 2019, pp. 2731-2740. https://doi.org/10.1021/acs.chemmater.8b04673.
Profiles