Chemistry of Materials, volume 31, issue 10, pages 3694-3699
Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12
Rui Iwasaki
1
,
Satoshi Hori
2
,
Ryoji Kanno
2
,
Takeaki Yajima
1
,
Daisuke Hirai
1
,
Yuki Kato
2, 3
,
Z. Hiroi
1
1
Institute for Solid state Physics, University of Tokyo, Kashiwa, Chiba 277-8581, Japan
|
3
Advanced Material Engineering Division Higashifuji Technical Center, Toyota Motor Corporation, 1200 Mishuku, Susono, Shizuoka 410-1193, Japan
|
Publication type: Journal Article
Publication date: 2019-04-29
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Single crystals of the lithium-ion conductor Li10GeP2S12 have been successfully grown by the self-flux method and are studied by means of X-ray diffraction and impedance spectroscopy. The weak anisotropic ionic conductivity is observed to be 27 and 7 mS cm–1 in the [001] and [110] directions, respectively, at room temperature. Markedly, however, the activation energies are nearly equal, approximately 0.3 eV, in the two directions, which means that common diffusion paths along [110] dominate the long-range diffusion in Li10GeP2S12.
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Citations by publishers
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1 publication, 1.72%
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2
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Iwasaki R. et al. Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12 // Chemistry of Materials. 2019. Vol. 31. No. 10. pp. 3694-3699.
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Iwasaki R., Hori S., Kanno R., Yajima T., Hirai D., Kato Y., Hiroi Z. Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12 // Chemistry of Materials. 2019. Vol. 31. No. 10. pp. 3694-3699.
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TY - JOUR
DO - 10.1021/acs.chemmater.9b00420
UR - https://doi.org/10.1021/acs.chemmater.9b00420
TI - Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12
T2 - Chemistry of Materials
AU - Iwasaki, Rui
AU - Hori, Satoshi
AU - Hirai, Daisuke
AU - Kato, Yuki
AU - Hiroi, Z.
AU - Kanno, Ryoji
AU - Yajima, Takeaki
PY - 2019
DA - 2019/04/29 00:00:00
PB - American Chemical Society (ACS)
SP - 3694-3699
IS - 10
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2019_Iwasaki,
author = {Rui Iwasaki and Satoshi Hori and Daisuke Hirai and Yuki Kato and Z. Hiroi and Ryoji Kanno and Takeaki Yajima},
title = {Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.9b00420},
number = {10},
pages = {3694--3699},
doi = {10.1021/acs.chemmater.9b00420}
}
Cite this
MLA
Copy
Iwasaki, Rui, et al. “Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12.” Chemistry of Materials, vol. 31, no. 10, Apr. 2019, pp. 3694-3699. https://doi.org/10.1021/acs.chemmater.9b00420.