Chemistry of Materials

, volume 31 , issue 10 , pages 3694-3699

Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12

Rui Iwasaki ¹

Satoshi Hori ²

Ryoji Kanno ²

Takeaki Yajima ¹

Daisuke Hirai ¹

Yuki Kato ^{2, 3}

Z. Hiroi ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Institute for Solid state Physics, University of Tokyo, Kashiwa, Chiba 277-8581, Japan |

Institute of Innovative Research (IIR), All-Solid-State Battery Unit, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8502, Japan |

Advanced Material Engineering Division Higashifuji Technical Center, Toyota Motor Corporation, 1200 Mishuku, Susono, Shizuoka 410-1193, Japan |

Publication type: Journal Article

Publication date: 2019-04-29

American Chemical Society (ACS)

Chemistry of Materials

scimago Q1

wos Q1

SJR: 2.065

CiteScore: 12.0

Impact factor: 7.0

ISSN: 08974756, 15205002

DOI: 10.1021/acs.chemmater.9b00420

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Materials Chemistry

General Chemistry

General Chemical Engineering

Abstract

Single crystals of the lithium-ion conductor Li10GeP2S12 have been successfully grown by the self-flux method and are studied by means of X-ray diffraction and impedance spectroscopy. The weak anisotropic ionic conductivity is observed to be 27 and 7 mS cm–1 in the [001] and [110] directions, respectively, at room temperature. Markedly, however, the activation energies are nearly equal, approximately 0.3 eV, in the two directions, which means that common diffusion paths along [110] dominate the long-range diffusion in Li10GeP2S12.

Found

1 citation

Voropaeva Daria

PhD in Chemistry

33 publications, 510 citations, 18 reviews

h-index: 13

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Green technologies

Lithium-ion batteries

Membrane materials

Sodium-ion batteries

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GOST |

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Iwasaki R. et al. Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12 // Chemistry of Materials. 2019. Vol. 31. No. 10. pp. 3694-3699.

GOST all authors (up to 50) Copy

Iwasaki R., Hori S., Kanno R., Yajima T., Hirai D., Kato Y., Hiroi Z. Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12 // Chemistry of Materials. 2019. Vol. 31. No. 10. pp. 3694-3699.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.chemmater.9b00420

UR - https://doi.org/10.1021/acs.chemmater.9b00420

TI - Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12

T2 - Chemistry of Materials

AU - Iwasaki, Rui

AU - Hori, Satoshi

AU - Kanno, Ryoji

AU - Yajima, Takeaki

AU - Hirai, Daisuke

AU - Kato, Yuki

AU - Hiroi, Z.

PY - 2019

DA - 2019/04/29

PB - American Chemical Society (ACS)

SP - 3694-3699

IS - 10

VL - 31

SN - 0897-4756

SN - 1520-5002

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Iwasaki,

author = {Rui Iwasaki and Satoshi Hori and Ryoji Kanno and Takeaki Yajima and Daisuke Hirai and Yuki Kato and Z. Hiroi},

title = {Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12},

journal = {Chemistry of Materials},

year = {2019},

volume = {31},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/acs.chemmater.9b00420},

number = {10},

pages = {3694--3699},

doi = {10.1021/acs.chemmater.9b00420}

}

MLA

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MLA Copy

Iwasaki, Rui, et al. “Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12.” Chemistry of Materials, vol. 31, no. 10, Apr. 2019, pp. 3694-3699. https://doi.org/10.1021/acs.chemmater.9b00420.

Publisher

American Chemical Society (ACS)

Journal

Chemistry of Materials

scimago Q1

wos Q1

SJR

2.065

CiteScore

12.0

Impact factor

7.0

ISSN

08974756 (Print)

15205002 (Electronic)