Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes
Тип публикации: Journal Article
Дата публикации: 2020-07-13
scimago Q1
wos Q1
БС1
SJR: 16.455
CiteScore: 100.5
Impact factor: 55.8
ISSN: 00092665, 15206890
PubMed ID:
32657576
General Chemistry
Краткое описание
Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes nowadays allow chemists to easily access these strained rings with high diastereo- and enantiomeric ratios. In turn, this development has created a paradigm shift for the synthesis of stereodefined acyclic molecules though selective carbon-carbon bond cleavage. Through chosen illustrative examples, we aim to show in this review that the cleavage of cyclopropane is a powerful approach to reveal sp3 stereocenters in acyclic systems. The application of these concepts was illustrated by the total syntheses of several natural products and other important molecules, further showing the power of these strategies as a powerful tool in organic synthesis.
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Cohen Y., Cohen A., Marek I. Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes // Chemical Reviews. 2020. Vol. 121. No. 1. pp. 140-161.
ГОСТ со всеми авторами (до 50)
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Cohen Y., Cohen A., Marek I. Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes // Chemical Reviews. 2020. Vol. 121. No. 1. pp. 140-161.
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TY - JOUR
DO - 10.1021/acs.chemrev.0c00167
UR - https://doi.org/10.1021/acs.chemrev.0c00167
TI - Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes
T2 - Chemical Reviews
AU - Cohen, Yair
AU - Cohen, Anthony
AU - Marek, Ilan
PY - 2020
DA - 2020/07/13
PB - American Chemical Society (ACS)
SP - 140-161
IS - 1
VL - 121
PMID - 32657576
SN - 0009-2665
SN - 1520-6890
ER -
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@article{2020_Cohen,
author = {Yair Cohen and Anthony Cohen and Ilan Marek},
title = {Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes},
journal = {Chemical Reviews},
year = {2020},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.chemrev.0c00167},
number = {1},
pages = {140--161},
doi = {10.1021/acs.chemrev.0c00167}
}
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MLA
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Cohen, Yair, et al. “Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes.” Chemical Reviews, vol. 121, no. 1, Jul. 2020, pp. 140-161. https://doi.org/10.1021/acs.chemrev.0c00167.