Chemical Reviews, volume 121, issue 1, pages 140-161
Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes
Publication type: Journal Article
Publication date: 2020-07-13
Journal:
Chemical Reviews
Q1
Q1
SJR: 17.828
CiteScore: 106.0
Impact factor: 51.4
ISSN: 00092665, 15206890
General Chemistry
Abstract
Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes nowadays allow chemists to easily access these strained rings with high diastereo- and enantiomeric ratios. In turn, this development has created a paradigm shift for the synthesis of stereodefined acyclic molecules though selective carbon-carbon bond cleavage. Through chosen illustrative examples, we aim to show in this review that the cleavage of cyclopropane is a powerful approach to reveal sp3 stereocenters in acyclic systems. The application of these concepts was illustrated by the total syntheses of several natural products and other important molecules, further showing the power of these strategies as a powerful tool in organic synthesis.
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Cohen Y., Cohen A., Marek I. Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes // Chemical Reviews. 2020. Vol. 121. No. 1. pp. 140-161.
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Cohen Y., Cohen A., Marek I. Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes // Chemical Reviews. 2020. Vol. 121. No. 1. pp. 140-161.
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TY - JOUR
DO - 10.1021/acs.chemrev.0c00167
UR - https://doi.org/10.1021/acs.chemrev.0c00167
TI - Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes
T2 - Chemical Reviews
AU - Cohen, Yair
AU - Cohen, Anthony
AU - Marek, Ilan
PY - 2020
DA - 2020/07/13
PB - American Chemical Society (ACS)
SP - 140-161
IS - 1
VL - 121
SN - 0009-2665
SN - 1520-6890
ER -
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@article{2020_Cohen,
author = {Yair Cohen and Anthony Cohen and Ilan Marek},
title = {Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes},
journal = {Chemical Reviews},
year = {2020},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.chemrev.0c00167},
number = {1},
pages = {140--161},
doi = {10.1021/acs.chemrev.0c00167}
}
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Cohen, Yair, et al. “Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes.” Chemical Reviews, vol. 121, no. 1, Jul. 2020, pp. 140-161. https://doi.org/10.1021/acs.chemrev.0c00167.