Chemical Reviews, volume 116, issue 1, pages 140-162

Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction

John Christopher Bachman
Sokseiha Muy
Hao-Hsun Chang
Nir Pour
Simon F. Lux 1
Odysseas Paschos 2
Filippo Maglia 2
Saskia Lupart 2
Peter Lamp 2
1
 
BMW Group Technology Office USA, Mountain View, California 94043, United States
2
 
Research Battery Technology, BMW Group, Munich 80788, Germany
Publication typeJournal Article
Publication date2015-12-29
Journal: Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor62.1
ISSN00092665, 15206890
General Chemistry
Abstract
This Review is focused on ion-transport mechanisms and fundamental properties of solid-state electrolytes to be used in electrochemical energy-storage systems. Properties of the migrating species significantly affecting diffusion, including the valency and ionic radius, are discussed. The natures of the ligand and metal composing the skeleton of the host framework are analyzed and shown to have large impacts on the performance of solid-state electrolytes. A comprehensive identification of the candidate migrating species and structures is carried out. Not only the bulk properties of the conductors are explored, but the concept of tuning the conductivity through interfacial effects-specifically controlling grain boundaries and strain at the interfaces-is introduced. High-frequency dielectric constants and frequencies of low-energy optical phonons are shown as examples of properties that correlate with activation energy across many classes of ionic conductors. Experimental studies and theoretical results are discussed in parallel to give a pathway for further improvement of solid-state electrolytes. Through this discussion, the present Review aims to provide insight into the physical parameters affecting the diffusion process, to allow for more efficient and target-oriented research on improving solid-state ion conductors.

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GOST Copy
Bachman J. C. et al. Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction // Chemical Reviews. 2015. Vol. 116. No. 1. pp. 140-162.
GOST all authors (up to 50) Copy
Bachman J. C., Muy S., Grimaud A., Chang H., Pour N., Lux S. F., Paschos O., Maglia F., Lupart S., Lamp P., Giordano L., Shao-Horn Y. Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction // Chemical Reviews. 2015. Vol. 116. No. 1. pp. 140-162.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.chemrev.5b00563
UR - https://doi.org/10.1021/acs.chemrev.5b00563
TI - Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
T2 - Chemical Reviews
AU - Bachman, John Christopher
AU - Chang, Hao-Hsun
AU - Pour, Nir
AU - Lux, Simon F.
AU - Paschos, Odysseas
AU - Lupart, Saskia
AU - Lamp, Peter
AU - Muy, Sokseiha
AU - Grimaud, A.
AU - Maglia, Filippo
AU - Giordano, Livia
AU - Shao-Horn, Yang
PY - 2015
DA - 2015/12/29 00:00:00
PB - American Chemical Society (ACS)
SP - 140-162
IS - 1
VL - 116
SN - 0009-2665
SN - 1520-6890
ER -
BibTex |
Cite this
BibTex Copy
@article{2015_Bachman,
author = {John Christopher Bachman and Hao-Hsun Chang and Nir Pour and Simon F. Lux and Odysseas Paschos and Saskia Lupart and Peter Lamp and Sokseiha Muy and A. Grimaud and Filippo Maglia and Livia Giordano and Yang Shao-Horn},
title = {Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction},
journal = {Chemical Reviews},
year = {2015},
volume = {116},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.chemrev.5b00563},
number = {1},
pages = {140--162},
doi = {10.1021/acs.chemrev.5b00563}
}
MLA
Cite this
MLA Copy
Bachman, John Christopher, et al. “Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction.” Chemical Reviews, vol. 116, no. 1, Dec. 2015, pp. 140-162. https://doi.org/10.1021/acs.chemrev.5b00563.
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