Chemical Reviews, volume 117, issue 13, pages 9016-9085
Recent Advances in Radical C-H Activation/Radical Cross-Coupling.
Publication type: Journal Article
Publication date: 2017-06-22
Journal:
Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 62.1
ISSN: 00092665, 15206890
General Chemistry
Abstract
Research and industrial interest in radical C-H activation/radical cross-coupling chemistry has continuously grown over the past few decades. These reactions offer fascinating and unconventional approaches toward connecting molecular fragments with high atom- and step-economy that are often complementary to traditional methods. Success in this area of research was made possible through the development of photocatalysis and first-row transition metal catalysis along with the use of peroxides as radical initiators. This Review provides a brief and concise overview of the current status and latest methodologies using radicals or radical cations as key intermediates produced via radical C-H activation. This Review includes radical addition, radical cascade cyclization, radical/radical cross-coupling, coupling of radicals with M-R groups, and coupling of radical cations with nucleophiles (Nu).
Top-30
Citations by journals
|
20
40
60
80
100
120
|
|
|
Organic Letters
111 publications, 10.6%
|
|
|
Journal of Organic Chemistry
73 publications, 6.97%
|
|
|
Chemical Communications
49 publications, 4.68%
|
|
|
ACS Catalysis
48 publications, 4.58%
|
|
|
Organic Chemistry Frontiers
47 publications, 4.49%
|
|
|
Advanced Synthesis and Catalysis
47 publications, 4.49%
|
|
|
Organic and Biomolecular Chemistry
46 publications, 4.39%
|
|
|
Angewandte Chemie - International Edition
43 publications, 4.11%
|
|
|
Angewandte Chemie
43 publications, 4.11%
|
|
|
Journal of the American Chemical Society
41 publications, 3.92%
|
|
|
European Journal of Organic Chemistry
36 publications, 3.44%
|
|
|
Chemical Science
27 publications, 2.58%
|
|
|
Chemistry - A European Journal
24 publications, 2.29%
|
|
|
Tetrahedron Letters
21 publications, 2.01%
|
|
|
Green Chemistry
20 publications, 1.91%
|
|
|
Asian Journal of Organic Chemistry
18 publications, 1.72%
|
|
|
Tetrahedron
17 publications, 1.62%
|
|
|
Nature Communications
15 publications, 1.43%
|
|
|
Chinese Journal of Organic Chemistry
11 publications, 1.05%
|
|
|
Chemical Reviews
11 publications, 1.05%
|
|
|
Synlett
11 publications, 1.05%
|
|
|
New Journal of Chemistry
10 publications, 0.96%
|
|
|
Synthesis
9 publications, 0.86%
|
|
|
ChemCatChem
9 publications, 0.86%
|
|
|
Chemical Society Reviews
9 publications, 0.86%
|
|
|
Chinese Journal of Chemistry
8 publications, 0.76%
|
|
|
Organometallics
8 publications, 0.76%
|
|
|
Chemical Record
7 publications, 0.67%
|
|
|
Beilstein Journal of Organic Chemistry
6 publications, 0.57%
|
|
|
20
40
60
80
100
120
|
Citations by publishers
|
50
100
150
200
250
300
350
|
|
|
American Chemical Society (ACS)
318 publications, 30.37%
|
|
|
Wiley
286 publications, 27.32%
|
|
|
Royal Society of Chemistry (RSC)
227 publications, 21.68%
|
|
|
Elsevier
103 publications, 9.84%
|
|
|
Springer Nature
37 publications, 3.53%
|
|
|
Thieme
22 publications, 2.1%
|
|
|
Shanghai Institute of Organic Chemistry
11 publications, 1.05%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
10 publications, 0.96%
|
|
|
Beilstein-Institut
6 publications, 0.57%
|
|
|
American Association for the Advancement of Science (AAAS)
6 publications, 0.57%
|
|
|
The Chemical Society of Japan
4 publications, 0.38%
|
|
|
Pleiades Publishing
2 publications, 0.19%
|
|
|
Frontiers Media S.A.
2 publications, 0.19%
|
|
|
Taylor & Francis
2 publications, 0.19%
|
|
|
Akademiai Kiado
1 publication, 0.1%
|
|
|
Bentham Science
1 publication, 0.1%
|
|
|
The Electrochemical Society
1 publication, 0.1%
|
|
|
Chinese Chemical Society
1 publication, 0.1%
|
|
|
The Japan Institute of Heterocyclic Chemistry
1 publication, 0.1%
|
|
|
Walter de Gruyter
1 publication, 0.1%
|
|
|
Research Square Platform LLC
1 publication, 0.1%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.1%
|
|
|
50
100
150
200
250
300
350
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024,2025],"ids":[0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","",""],"datasets":[{"label":"Citations number","data":[26,176,183,153,158,148,120,81,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.48","16.81","17.48","14.61","15.09","14.14","11.46","7.74","0.19"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organic Letters","Journal of Organic Chemistry","Chemical Communications","ACS Catalysis","Organic Chemistry Frontiers","Advanced Synthesis and Catalysis","Organic and Biomolecular Chemistry","Angewandte Chemie - International Edition","Angewandte Chemie","Journal of the American Chemical Society","European Journal of Organic Chemistry","Chemical Science","Chemistry - A European Journal","Tetrahedron Letters","Green Chemistry","Asian Journal of Organic Chemistry","Tetrahedron","Nature Communications","Chinese Journal of Organic Chemistry","Chemical Reviews","Synlett","New Journal of Chemistry","Synthesis","ChemCatChem","Chemical Society Reviews","Chinese Journal of Chemistry","Organometallics","Chemical Record","Beilstein Journal of Organic Chemistry"],"ids":[3315,8697,9073,4873,3991,3906,541,19215,25450,4813,19472,9646,24708,6133,1017,9409,3439,3231,11696,13718,10217,1404,10934,10149,20586,7222,1409,22413,21928],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/6EJSsoiR4fNMNMPFBpMh5yKuYKcPXJDQKvKVeEMy_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/ex6KJoZujZOZFZh7jGfeHauiftuB3CI7iwJVFRDg_medium.webp"],"datasets":[{"label":"","data":[111,73,49,48,47,47,46,43,43,41,36,27,24,21,20,18,17,15,11,11,11,10,9,9,9,8,8,7,6],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[10.6,6.97,4.68,4.58,4.49,4.49,4.39,4.11,4.11,3.92,3.44,2.58,2.29,2.01,1.91,1.72,1.62,1.43,1.05,1.05,1.05,0.96,0.86,0.86,0.86,0.76,0.76,0.67,0.57],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Elsevier","Springer Nature","Thieme","Shanghai Institute of Organic Chemistry","Multidisciplinary Digital Publishing Institute (MDPI)","Beilstein-Institut","American Association for the Advancement of Science (AAAS)","The Chemical Society of Japan","Pleiades Publishing","Frontiers Media S.A.","Taylor & Francis","Akademiai Kiado","Bentham Science","The Electrochemical Society","Chinese Chemical Society","The Japan Institute of Heterocyclic Chemistry","Walter de Gruyter","Research Square Platform LLC","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,123,17,8,135,8960,202,6139,189,6950,101,208,18,7012,39,6916,7008,9411,4,9418,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/6EJSsoiR4fNMNMPFBpMh5yKuYKcPXJDQKvKVeEMy_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/ex6KJoZujZOZFZh7jGfeHauiftuB3CI7iwJVFRDg_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/ktSZPrGjOMvauY6mn7jk8bqo3Af0S6abv653w90B_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/lZ7ODGrM6PfzyKRLOh0nsqTcgHBMMYr9TkD5skBH_medium.webp","\/storage\/images\/resized\/doUaFUZdxUEQjLi1TwZjGHi8HXYNWWSk04dSC6Xh_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/InHyt3GE52gi4tI9oOoCFm6bIAJLehb2BS5NO7Qs_medium.webp","\/storage\/images\/resized\/SovkqI6gX6to8o5XBnS9RNxEOYVicn7hatkMzrvl_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[318,286,227,103,37,22,11,10,6,6,4,2,2,2,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[30.37,27.32,21.68,9.84,3.53,2.1,1.05,0.96,0.57,0.57,0.38,0.19,0.19,0.19,0.1,0.1,0.1,0.1,0.1,0.1,0.1,0.1],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0,0,1,0,0,0,0],"percentage":["0","0.1","0","0","0.1","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,5,4,7,14,8,4,1,0],"percentage":["0","0.48","0.38","0.67","1.34","0.76","0.38","0.1","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[4,20,17,15,22,22,19,15,0],"percentage":["0.38","1.91","1.62","1.43","2.1","2.1","1.81","1.43","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[22,149,156,129,120,97,94,60,0],"percentage":["2.1","14.23","14.9","12.32","11.46","9.26","8.98","5.73","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,6,2,1,21,3,5,2],"percentage":["0","0.1","0.57","0.19","0.1","2.01","0.29","0.48","0.19"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,2,0,1,4,2,0,0,0],"percentage":["0","0.19","0","0.1","0.38","0.19","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[2,7,9,9,17,9,13,5,0],"percentage":["0.19","0.67","0.86","0.86","1.62","0.86","1.24","0.48","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[7,59,48,43,36,38,30,24,0],"percentage":["0.67","5.64","4.58","4.11","3.44","3.63","2.87","2.29","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[13,99,106,90,94,70,66,45,0],"percentage":["1.24","9.46","10.12","8.6","8.98","6.69","6.3","4.3","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[4,9,20,10,7,29,11,7,2],"percentage":["0.38","0.86","1.91","0.96","0.67","2.77","1.05","0.67","0.19"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Yi H. et al. Recent Advances in Radical C-H Activation/Radical Cross-Coupling. // Chemical Reviews. 2017. Vol. 117. No. 13. pp. 9016-9085.
GOST all authors (up to 50)
Copy
Yi H., Zhang G., Wang H., Huang Z., Wang J., Singh A. K., Lei A. Recent Advances in Radical C-H Activation/Radical Cross-Coupling. // Chemical Reviews. 2017. Vol. 117. No. 13. pp. 9016-9085.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemrev.6b00620
UR - https://doi.org/10.1021/acs.chemrev.6b00620
TI - Recent Advances in Radical C-H Activation/Radical Cross-Coupling.
T2 - Chemical Reviews
AU - Zhang, Guoting
AU - Wang, Huamin
AU - Huang, Zhiyuan
AU - Wang, Jue
AU - Singh, Atul K
AU - Lei, Aiwen
AU - Yi, Hong
PY - 2017
DA - 2017/06/22 00:00:00
PB - American Chemical Society (ACS)
SP - 9016-9085
IS - 13
VL - 117
SN - 0009-2665
SN - 1520-6890
ER -
Cite this
BibTex
Copy
@article{2017_Yi,
author = {Guoting Zhang and Huamin Wang and Zhiyuan Huang and Jue Wang and Atul K Singh and Aiwen Lei and Hong Yi},
title = {Recent Advances in Radical C-H Activation/Radical Cross-Coupling.},
journal = {Chemical Reviews},
year = {2017},
volume = {117},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.chemrev.6b00620},
number = {13},
pages = {9016--9085},
doi = {10.1021/acs.chemrev.6b00620}
}
Cite this
MLA
Copy
Yi, Hong, et al. “Recent Advances in Radical C-H Activation/Radical Cross-Coupling..” Chemical Reviews, vol. 117, no. 13, Jun. 2017, pp. 9016-9085. https://doi.org/10.1021/acs.chemrev.6b00620.