Chemical Reviews, volume 117, issue 13, pages 8622-8648
The Essential Role of Bond Energetics in C-H Activation/Functionalization.
Publication type: Journal Article
Publication date: 2017-03-10
Journal:
Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 62.1
ISSN: 00092665, 15206890
General Chemistry
Abstract
The most fundamental concepts in chemistry are structure, energetics, reactivity and their inter-relationships, which are indispensable for promoting chemistry into a rational science. In this regard, bond energy, the intrinsic determinant directly related to structure and reactivity, should be most essential in serving as a quantitative basis for the design and understanding of organic transformations. Although C-H activation/functionalization have drawn tremendous research attention and flourished during the past decades, understanding the governing rules of bond energetics in these processes is still fragmentary and seems applicable only to limited cases, such as metal-oxo-mediated hydrogen atom abstraction. Despite the complexity of C-H activation/functionalization and the difficulties in measuring bond energies both for the substrates and intermediates, this is definitely a very important issue that should be more generally contemplated. To this end, this review is rooted in the energetic aspects of C-H activation/functionalization, which were previously rarely discussed in detail. Starting with a concise but necessary introduction of various classical methods for measuring heterolytic and homolytic energies for C-H bonds, the present review provides examples that applied the concept and values of C-H bond energy in rationalizing the observations associated with reactivity and/or selectivity in C-H activation/functionalization.
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Xue X. et al. The Essential Role of Bond Energetics in C-H Activation/Functionalization. // Chemical Reviews. 2017. Vol. 117. No. 13. pp. 8622-8648.
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Xue X., Ji P., Zhou B., Cheng J. The Essential Role of Bond Energetics in C-H Activation/Functionalization. // Chemical Reviews. 2017. Vol. 117. No. 13. pp. 8622-8648.
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TY - JOUR
DO - 10.1021/acs.chemrev.6b00664
UR - https://doi.org/10.1021/acs.chemrev.6b00664
TI - The Essential Role of Bond Energetics in C-H Activation/Functionalization.
T2 - Chemical Reviews
AU - Zhou, Biying
AU - Xue, Xiao-Song
AU - Cheng, Jin-Pei
AU - Ji, Pengju
PY - 2017
DA - 2017/03/10 00:00:00
PB - American Chemical Society (ACS)
SP - 8622-8648
IS - 13
VL - 117
SN - 0009-2665
SN - 1520-6890
ER -
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@article{2017_Xue,
author = {Biying Zhou and Xiao-Song Xue and Jin-Pei Cheng and Pengju Ji},
title = {The Essential Role of Bond Energetics in C-H Activation/Functionalization.},
journal = {Chemical Reviews},
year = {2017},
volume = {117},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.chemrev.6b00664},
number = {13},
pages = {8622--8648},
doi = {10.1021/acs.chemrev.6b00664}
}
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Xue, Xiao-Song, et al. “The Essential Role of Bond Energetics in C-H Activation/Functionalization..” Chemical Reviews, vol. 117, no. 13, Mar. 2017, pp. 8622-8648. https://doi.org/10.1021/acs.chemrev.6b00664.