Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation
Тип публикации: Journal Article
Дата публикации: 2018-07-05
scimago Q1
wos Q2
БС1
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Краткое описание
In the production of poly(vinyl alcohol), the raw materials methyl acetate (MeOAc) and methanol (MeOH) exist as a homogeneous azeotropic mixture. Twenty-five kinds of ionic liquids, composed of five types of cations and five types of anions, were studied using the COSMO-SAC method. The σ-profile data for each component and the selectivity at infinite dilution (S∞) were calculated and analyzed, respectively. 1-Hexyl-3-methylimidazolium chloride ([HMIM][Cl]) and 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]) were selected as suitable entrainers based on the COSMO-SAC method. The binary interaction parameters of the NRTL model of the MeOAc/ionic liquid and MeOH/ionic liquid systems were regressed. The conceptual design for the separation of MeOAc and MeOH using ionic liquids as entrainers was investigated. The comparison of two processes using two entrainers was carried out from an economic perspective. The total annual cost (TAC) of the process using [HMIM][Cl] as an entrainer can be reduced by 16.5% com...
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ГОСТ
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Zhu Z. et al. Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation // Industrial & Engineering Chemistry Research. 2018. Vol. 57. No. 29. pp. 9656-9664.
ГОСТ со всеми авторами (до 50)
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Zhu Z., Geng X., He W., Chen C., Wang Y., Gao J. Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation // Industrial & Engineering Chemistry Research. 2018. Vol. 57. No. 29. pp. 9656-9664.
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TY - JOUR
DO - 10.1021/acs.iecr.8b01355
UR - https://doi.org/10.1021/acs.iecr.8b01355
TI - Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation
T2 - Industrial & Engineering Chemistry Research
AU - Zhu, Zhaoyou
AU - Geng, Xueli
AU - He, Wei
AU - Chen, Chao
AU - Wang, Yinglong
AU - Gao, Jun
PY - 2018
DA - 2018/07/05
PB - American Chemical Society (ACS)
SP - 9656-9664
IS - 29
VL - 57
SN - 0888-5885
SN - 1520-5045
ER -
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BibTex (до 50 авторов)
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@article{2018_Zhu,
author = {Zhaoyou Zhu and Xueli Geng and Wei He and Chao Chen and Yinglong Wang and Jun Gao},
title = {Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation},
journal = {Industrial & Engineering Chemistry Research},
year = {2018},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.iecr.8b01355},
number = {29},
pages = {9656--9664},
doi = {10.1021/acs.iecr.8b01355}
}
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MLA
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Zhu, Zhaoyou, et al. “Computer-Aided Screening of Ionic Liquids As Entrainers for Separating Methyl Acetate and Methanol via Extractive Distillation.” Industrial & Engineering Chemistry Research, vol. 57, no. 29, Jul. 2018, pp. 9656-9664. https://doi.org/10.1021/acs.iecr.8b01355.