Inorganic Chemistry, volume 59, issue 12, pages 7928-7933
Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes
Hiroki Asaba
1
,
Takanori Iwasaki
1
,
Masahiro Hatazawa
1
,
Jingyuan Deng
1
,
Haruki Nagae
2
,
Kazushi Mashima
2
,
Kyoko Nozaki
1
Publication type: Journal Article
Publication date: 2020-06-03
Journal:
Inorganic Chemistry
Q1
Q1
SJR: 0.928
CiteScore: 7.6
Impact factor: 4.3
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Heteromultimetallic complexes consisting of three Co(II) ions and one lanthanide ion were synthesized and applied to the alternating copolymerization of CO2 and cyclohexene oxide. Unlike the conventional cobalt(III) salen complexes, the high thermal stability of the present catalyst allowed us to reach a turnover number of 13000, one of the highest values ever reported for multimetallic systems. The chain propagation was first-order to the catalyst, suggesting a cooperative behavior of the metal centers.
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GOST
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Asaba H. et al. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes // Inorganic Chemistry. 2020. Vol. 59. No. 12. pp. 7928-7933.
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Asaba H., Iwasaki T., Hatazawa M., Deng J., Nagae H., Mashima K., Nozaki K. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes // Inorganic Chemistry. 2020. Vol. 59. No. 12. pp. 7928-7933.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01156
UR - https://doi.org/10.1021/acs.inorgchem.0c01156
TI - Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes
T2 - Inorganic Chemistry
AU - Asaba, Hiroki
AU - Iwasaki, Takanori
AU - Hatazawa, Masahiro
AU - Deng, Jingyuan
AU - Nagae, Haruki
AU - Mashima, Kazushi
AU - Nozaki, Kyoko
PY - 2020
DA - 2020/06/03
PB - American Chemical Society (ACS)
SP - 7928-7933
IS - 12
VL - 59
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Asaba,
author = {Hiroki Asaba and Takanori Iwasaki and Masahiro Hatazawa and Jingyuan Deng and Haruki Nagae and Kazushi Mashima and Kyoko Nozaki},
title = {Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.inorgchem.0c01156},
number = {12},
pages = {7928--7933},
doi = {10.1021/acs.inorgchem.0c01156}
}
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Asaba, Hiroki, et al. “Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt–Lanthanide Mixed Multinuclear Complexes.” Inorganic Chemistry, vol. 59, no. 12, Jun. 2020, pp. 7928-7933. https://doi.org/10.1021/acs.inorgchem.0c01156.