Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex.
3
Synchrotron SOLEIL, L’orme des Merisiers, Saint Aubin BP 48, 91192 Gif-Sur-Yvette, France
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Publication type: Journal Article
Publication date: 2020-08-26
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32846087
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The chemical properties of actinide materials are often predefined and described based on the data available for isostructural species. This is the case for potassium plutonyl (PuVI) carbonate, K4PuVIO2(CO3)3(cr), a complex relevant for nuclear technology and the environment, of which the crystallographic and thermodynamic properties of which are still lacking. We report here the synthesis and characterization of PuVI achieved by single-crystal X-ray diffraction analysis and high-energy-resolution fluorescence-detected X-ray absorption near-edge structure at the Pu M4-edge coupled with electronic structure calculations. The crystallographic properties of PuVI are compared with isostructural uranium (U) and neptunium (Np) compounds. Actinyl (AnVI) axial bond lengths, [O-AnVI-O]2+, are correlated between solid, K4AnVIO2(CO3)3(cr), and aqueous, [AnVIO2(CO3)3]4-(aq) species for the UVI-NpVI-PuVI series. The spectroscopic data are compared to KPuVO2CO3(cr) and PuIVO2(cr) to tackle the trend in the electronic structure of PuVI regarding the oxidation state changes and local structural modifications around the Pu atom.
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Total citations:
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Pidchenko I. et al. Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex. // Inorganic Chemistry. 2020. Vol. 59. No. 17. pp. 11889-11893.
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Pidchenko I., März J., Hunault M. O. J. Y., Bauters S., Butorin S. M., Kvashnina K. Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex. // Inorganic Chemistry. 2020. Vol. 59. No. 17. pp. 11889-11893.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01335
UR - https://doi.org/10.1021/acs.inorgchem.0c01335
TI - Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex.
T2 - Inorganic Chemistry
AU - Pidchenko, Ivan
AU - März, Juliane
AU - Hunault, Myrtille O. J. Y.
AU - Bauters, Stephen
AU - Butorin, Sergei M.
AU - Kvashnina, Kristina
PY - 2020
DA - 2020/08/26
PB - American Chemical Society (ACS)
SP - 11889-11893
IS - 17
VL - 59
PMID - 32846087
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2020_Pidchenko,
author = {Ivan Pidchenko and Juliane März and Myrtille O. J. Y. Hunault and Stephen Bauters and Sergei M. Butorin and Kristina Kvashnina},
title = {Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex.},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.inorgchem.0c01335},
number = {17},
pages = {11889--11893},
doi = {10.1021/acs.inorgchem.0c01335}
}
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MLA
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Pidchenko, Ivan, et al. “Synthesis, Structural, and Electronic Properties of K4PuVIO2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex..” Inorganic Chemistry, vol. 59, no. 17, Aug. 2020, pp. 11889-11893. https://doi.org/10.1021/acs.inorgchem.0c01335.