Inorganic Chemistry, volume 61, issue 1, pages 384-398
Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides
Gutorova S V
1
,
Matveev Petr I
1
,
Lemport P S
1
,
Trigub A L
1, 2
,
Pozdeev A S
1
,
Yatsenko A. V.
1
,
Tarasevich B N
1
,
Konopkina E A
1
,
Khult E K
3
,
Roznyatovsky V A
1
,
Nelyubina Yu V
4
,
Isakovskaya K L
5
,
Petrov V. S.
1
,
Aldoshin A S
1
,
Ustynyuk Yu A
1
,
Kalmykov S N
1
,
Publication type: Journal Article
Publication date: 2021-12-22
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reprocessing of spent nuclear fuel (SNF) is an important task in a frame of ecology and rational use of natural resources. Uranium, as the main component of SNF (>95%), can be recovered for further use as fresh nuclear fuel. To minimize an amount of solid radioactive waste generated during SNF reprocessing, new extractants are under investigation. Diamides of 1,10-phenanthroline-2,9-dicarboxylic acid are perspective tetradentate N-donor ligands that form strong complexes with f-elements, which are soluble in polar organic solvents. As an example of three ligands of this class, we conducted a comparative study and showed how the substituent in the amide functional group affects the extraction ability toward uranyl nitrate from nitric acid media. We have performed a careful study (NMR, FT-IR, XRD, RMC-EXAFS) of the structures of synthesized complexes of new ligands with uranyl nitrate and used quantum mechanical calculations to explain the discovered regularities through.
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1 publication, 5.26%
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1 publication, 5.26%
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1 publication, 5.26%
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1 publication, 5.26%
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1
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Citations by publishers
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2
3
4
5
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6 publications, 31.58%
|
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|
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4 publications, 21.05%
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3 publications, 15.79%
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2 publications, 10.53%
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Elsevier
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2 publications, 10.53%
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1 publication, 5.26%
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Springer Nature
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Springer Nature
1 publication, 5.26%
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1
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3
4
5
6
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Gutorova S. V. et al. Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides // Inorganic Chemistry. 2021. Vol. 61. No. 1. pp. 384-398.
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Gutorova S. V., Matveev P. I., Lemport P. S., Trigub A. L., Pozdeev A. S., Yatsenko A. V., Tarasevich B. N., Konopkina E. A., Khult E. K., Roznyatovsky V. A., Nelyubina Yu. V., Isakovskaya K. L., Khrustalev V. N., Petrov V. S., Aldoshin A. S., Ustynyuk Yu. A., Petrov V. G., Kalmykov S. N., Nenajdenko V. G. Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides // Inorganic Chemistry. 2021. Vol. 61. No. 1. pp. 384-398.
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TY - JOUR
DO - 10.1021/acs.inorgchem.1c02982
UR - https://doi.org/10.1021%2Facs.inorgchem.1c02982
TI - Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides
T2 - Inorganic Chemistry
AU - Gutorova, S V
AU - Lemport, P S
AU - Trigub, A L
AU - Pozdeev, A S
AU - Yatsenko, A. V.
AU - Konopkina, E A
AU - Khult, E K
AU - Roznyatovsky, V A
AU - Nelyubina, Yu V
AU - Isakovskaya, K L
AU - Petrov, V. S.
AU - Aldoshin, A S
AU - Ustynyuk, Yu A
AU - Kalmykov, S N
AU - Tarasevich, B N
AU - Matveev, Petr I
AU - Khrustalev, Victor N.
AU - Petrov, Vladimir G
AU - Nenajdenko, Valentine G.
PY - 2021
DA - 2021/12/22 00:00:00
PB - American Chemical Society (ACS)
SP - 384-398
IS - 1
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2021_Gutorova,
author = {S V Gutorova and P S Lemport and A L Trigub and A S Pozdeev and A. V. Yatsenko and E A Konopkina and E K Khult and V A Roznyatovsky and Yu V Nelyubina and K L Isakovskaya and V. S. Petrov and A S Aldoshin and Yu A Ustynyuk and S N Kalmykov and B N Tarasevich and Petr I Matveev and Victor N. Khrustalev and Vladimir G Petrov and Valentine G. Nenajdenko},
title = {Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides},
journal = {Inorganic Chemistry},
year = {2021},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021%2Facs.inorgchem.1c02982},
number = {1},
pages = {384--398},
doi = {10.1021/acs.inorgchem.1c02982}
}
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Gutorova, S. V., et al. “Structural Insight into Complexation Ability and Coordination of Uranyl Nitrate by 1,10-Phenanthroline-2,9-diamides.” Inorganic Chemistry, vol. 61, no. 1, Dec. 2021, pp. 384-398. https://doi.org/10.1021%2Facs.inorgchem.1c02982.