Inorganic Chemistry, volume 61, issue 42, pages 16586-16595
Niobium and Tantalum Halocyanide Clusters: The Complete Family
Publication type: Journal Article
Publication date: 2022-09-26
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide clusters with terminal cyanide ligands have been developed. Corresponding [M6X12(CN)12]4- (M = Nb, Ta; X = Cl, Br) can be accessed by ligand-exchange procedures from K4Nb6X18 (X = Cl, Br) and Bu4NCN, (Et4N)2[Ta6Cl18] and Bu4NCN and from [Ta6Br12(H2O)4Br2]·4H2O and KCN in moderate to high yields (50-80%). The products were isolated as Bu4N salts. The compounds were investigated both experimentally and by quantum chemistry, revealing correlations between structural, electrochemical, electrostatic, electronic, and topological features as a function of type of metal, halide, and charge.
Citations by journals
|
1
|
|
|
Journal of Structural Chemistry
|
Journal of Structural Chemistry
1 publication, 50%
|
|
Inorganic Chemistry
|
Inorganic Chemistry
1 publication, 50%
|
|
1
|
Citations by publishers
|
1
|
|
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 50%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
1 publication, 50%
|
|
1
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[2],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Structural Chemistry","Inorganic Chemistry"],"ids":[14105,24714],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Pleiades Publishing","American Chemical Society (ACS)"],"ids":[101,40],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shamshurin M. et al. Niobium and Tantalum Halocyanide Clusters: The Complete Family // Inorganic Chemistry. 2022. Vol. 61. No. 42. pp. 16586-16595.
GOST all authors (up to 50)
Copy
Shamshurin M., Gushchin A. L., Adonin S. A., Benassi E., Sokolov M. Niobium and Tantalum Halocyanide Clusters: The Complete Family // Inorganic Chemistry. 2022. Vol. 61. No. 42. pp. 16586-16595.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.2c01824
UR - https://doi.org/10.1021%2Facs.inorgchem.2c01824
TI - Niobium and Tantalum Halocyanide Clusters: The Complete Family
T2 - Inorganic Chemistry
AU - Shamshurin, Maxim
AU - Gushchin, Artem L
AU - Adonin, Sergey A
AU - Benassi, E.
AU - Sokolov, Maxim
PY - 2022
DA - 2022/09/26 00:00:00
PB - American Chemical Society (ACS)
SP - 16586-16595
IS - 42
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex
Copy
@article{2022_Shamshurin,
author = {Maxim Shamshurin and Artem L Gushchin and Sergey A Adonin and E. Benassi and Maxim Sokolov},
title = {Niobium and Tantalum Halocyanide Clusters: The Complete Family},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021%2Facs.inorgchem.2c01824},
number = {42},
pages = {16586--16595},
doi = {10.1021/acs.inorgchem.2c01824}
}
Cite this
MLA
Copy
Shamshurin, Maxim, et al. “Niobium and Tantalum Halocyanide Clusters: The Complete Family.” Inorganic Chemistry, vol. 61, no. 42, Sep. 2022, pp. 16586-16595. https://doi.org/10.1021%2Facs.inorgchem.2c01824.