Niobium and Tantalum Halocyanide Clusters: The Complete Family
Publication type: Journal Article
Publication date: 2022-09-26
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
36162107
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide clusters with terminal cyanide ligands have been developed. Corresponding [M6X12(CN)12]4- (M = Nb, Ta; X = Cl, Br) can be accessed by ligand-exchange procedures from K4Nb6X18 (X = Cl, Br) and Bu4NCN, (Et4N)2[Ta6Cl18] and Bu4NCN and from [Ta6Br12(H2O)4Br2]·4H2O and KCN in moderate to high yields (50-80%). The products were isolated as Bu4N salts. The compounds were investigated both experimentally and by quantum chemistry, revealing correlations between structural, electrochemical, electrostatic, electronic, and topological features as a function of type of metal, halide, and charge.
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Total citations:
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Citations from 2024:
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(66.66%)
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Shamshurin M. et al. Niobium and Tantalum Halocyanide Clusters: The Complete Family // Inorganic Chemistry. 2022. Vol. 61. No. 42. pp. 16586-16595.
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Shamshurin M., Gushchin A. L., Adonin S. A., Benassi E., Sokolov M. Niobium and Tantalum Halocyanide Clusters: The Complete Family // Inorganic Chemistry. 2022. Vol. 61. No. 42. pp. 16586-16595.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.2c01824
UR - https://doi.org/10.1021/acs.inorgchem.2c01824
TI - Niobium and Tantalum Halocyanide Clusters: The Complete Family
T2 - Inorganic Chemistry
AU - Shamshurin, Maxim
AU - Gushchin, Artem L
AU - Adonin, Sergey A
AU - Benassi, E.
AU - Sokolov, Maxim
PY - 2022
DA - 2022/09/26
PB - American Chemical Society (ACS)
SP - 16586-16595
IS - 42
VL - 61
PMID - 36162107
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2022_Shamshurin,
author = {Maxim Shamshurin and Artem L Gushchin and Sergey A Adonin and E. Benassi and Maxim Sokolov},
title = {Niobium and Tantalum Halocyanide Clusters: The Complete Family},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.inorgchem.2c01824},
number = {42},
pages = {16586--16595},
doi = {10.1021/acs.inorgchem.2c01824}
}
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MLA
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Shamshurin, Maxim, et al. “Niobium and Tantalum Halocyanide Clusters: The Complete Family.” Inorganic Chemistry, vol. 61, no. 42, Sep. 2022, pp. 16586-16595. https://doi.org/10.1021/acs.inorgchem.2c01824.