Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes
Publication type: Journal Article
Publication date: 2015-06-24
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
26107184
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two novel heteroligand o-semiquinonato-formazanato cobalt complexes [Co(3,6-SQ)(Form)] (1) and [Co(3,6-SQ)2(Form)] (2) (3,6-SQ is 3,6-di-tert-butyl-o-benzosemiquinonate radical anion; Form is 1,3,5-triphenylformazanate anion) were synthesized and characterized in detail. The molecular structures of [Co(3,6-SQ)(Form)] and [Co(3,6-SQ)2(Form)] were determined by X-ray analysis. Magnetic susceptibility measurements and spectroscopic studies have shown that square-planar complex 1 is diamagnetic with a residual paramagnetism due to antiferromagnetic exchange metal-ligand. Complex 2 includes cobalt(III) in the low-spin state and two anionic-radical o-semiquinonato and one formazanate ligand.
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Total citations:
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Citations from 2024:
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Protasenko N. A. et al. Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes // Inorganic Chemistry. 2015. Vol. 54. No. 13. pp. 6078-6080.
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Protasenko N. A., Poddel'sky A. I., Bogomyakov A. S., Fukin G. K., Cherkasov V. K. Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes // Inorganic Chemistry. 2015. Vol. 54. No. 13. pp. 6078-6080.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.5b00912
UR - https://doi.org/10.1021/acs.inorgchem.5b00912
TI - Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes
T2 - Inorganic Chemistry
AU - Protasenko, Natalia A
AU - Poddel'sky, Andrey I.
AU - Bogomyakov, Artem S
AU - Fukin, Georgy K.
AU - Cherkasov, Vladimir Kuzmich
PY - 2015
DA - 2015/06/24
PB - American Chemical Society (ACS)
SP - 6078-6080
IS - 13
VL - 54
PMID - 26107184
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2015_Protasenko,
author = {Natalia A Protasenko and Andrey I. Poddel'sky and Artem S Bogomyakov and Georgy K. Fukin and Vladimir Kuzmich Cherkasov},
title = {Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes},
journal = {Inorganic Chemistry},
year = {2015},
volume = {54},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.inorgchem.5b00912},
number = {13},
pages = {6078--6080},
doi = {10.1021/acs.inorgchem.5b00912}
}
Cite this
MLA
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Protasenko, Natalia A., et al. “Heteroligand o-Semiquinonato-Formazanato Cobalt Complexes.” Inorganic Chemistry, vol. 54, no. 13, Jun. 2015, pp. 6078-6080. https://doi.org/10.1021/acs.inorgchem.5b00912.