Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr)
Publication type: Journal Article
Publication date: 2017-01-30
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28135080
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The structural and magnetic properties of the two Ir(V) perovskites Ba2ScIrO6 and Sr2ScIrO6 were established. The structures were refined using a combined neutron and synchrotron data set. At room temperature the former has a cubic structure in space group Fm3̅m with a = 8.1450(3) Å, and the latter is monoclinic in P21/n with a = 5.6606(3) Å, b = 5.6366(3) Å, c = 7.9720(4) Å, and β = 89.977(5)°. Magnetization measurements show both oxides have magnetic moments close to zero as a consequence of strong spin-orbit coupling that results in a Jeff ≈ 0 ground state. The distortion of the IrO6 octahedra in Sr2ScIrO6 is insufficient to generate crystal field splitting strong enough to quench the spin-orbit coupling.
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Kayser P. et al. Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr) // Inorganic Chemistry. 2017. Vol. 56. No. 4. pp. 2204-2209.
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Kayser P., Kennedy B., Ranjbar B., Kimpton J. A., Avdeev M. Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr) // Inorganic Chemistry. 2017. Vol. 56. No. 4. pp. 2204-2209.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.6b02848
UR - https://doi.org/10.1021/acs.inorgchem.6b02848
TI - Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr)
T2 - Inorganic Chemistry
AU - Kayser, Paula
AU - Kennedy, Brendan
AU - Ranjbar, Ben
AU - Kimpton, Justin A.
AU - Avdeev, Maxim
PY - 2017
DA - 2017/01/30
PB - American Chemical Society (ACS)
SP - 2204-2209
IS - 4
VL - 56
PMID - 28135080
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Kayser,
author = {Paula Kayser and Brendan Kennedy and Ben Ranjbar and Justin A. Kimpton and Maxim Avdeev},
title = {Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr)},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.inorgchem.6b02848},
number = {4},
pages = {2204--2209},
doi = {10.1021/acs.inorgchem.6b02848}
}
Cite this
MLA
Copy
Kayser, Paula, et al. “Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr).” Inorganic Chemistry, vol. 56, no. 4, Jan. 2017, pp. 2204-2209. https://doi.org/10.1021/acs.inorgchem.6b02848.
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