Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester
Marina V Volostnykh
1, 2
,
Sergey E. Nefedov
3, 4
,
Gayane Kirakosyan
1, 3
,
Gayane A. Kirakosyan
4, 5
,
Yulia G. Gorbunova
1, 3, 4, 5
,
Aslan Tsivadze
1, 3
,
Aslan Yu. Tsivadze
4, 5
,
Alla G. Bessmertnykh-Lemeune
6
,
Christine Stern
2
,
Roger Guilard
2, 6
Publication type: Journal Article
Publication date: 2017-02-14
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28195721
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and structural characterization, both in solution by means of 1H and 31P NMR and UV-vis spectroscopies and in the solid state by X-ray diffraction on single crystal, of a series of gallium(III) and indium(III) meso-mono(diethoxyphosphoryl)porphyrins bearing different peripheral substituents as well as the corresponding monoesters and phosphonic acids are reported. This work describes the first example of the X-ray structure of a self-assembled dimer formed via strong binding between the oxygen atom of the phosphonate substituent and the gallium(III) cations of adjacent porphyrin molecules [Ga-O = 1.9708(13) Å].
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Total citations:
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Citations from 2024:
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(22%)
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Enakieva Y. Y. et al. Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester // Inorganic Chemistry. 2017. Vol. 56. No. 5. pp. 3055-3070.
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Enakieva Y. Y., Volostnykh M. V., Nefedov S. E., Kirakosyan G., Kirakosyan G. A., Gorbunova Y. G., Tsivadze A., Tsivadze A. Y., Bessmertnykh-Lemeune A., Bessmertnykh-Lemeune A. G., Stern C., Guilard R. Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester // Inorganic Chemistry. 2017. Vol. 56. No. 5. pp. 3055-3070.
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TY - JOUR
DO - 10.1021/acs.inorgchem.6b03160
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b03160
TI - Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester
T2 - Inorganic Chemistry
AU - Enakieva, Yulia Yu.
AU - Volostnykh, Marina V
AU - Nefedov, Sergey E.
AU - Kirakosyan, Gayane
AU - Kirakosyan, Gayane A.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
AU - Bessmertnykh-Lemeune, Alla
AU - Bessmertnykh-Lemeune, Alla G.
AU - Stern, Christine
AU - Guilard, Roger
PY - 2017
DA - 2017/02/14
PB - American Chemical Society (ACS)
SP - 3055-3070
IS - 5
VL - 56
PMID - 28195721
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Enakieva,
author = {Yulia Yu. Enakieva and Marina V Volostnykh and Sergey E. Nefedov and Gayane Kirakosyan and Gayane A. Kirakosyan and Yulia G. Gorbunova and Aslan Tsivadze and Aslan Yu. Tsivadze and Alla Bessmertnykh-Lemeune and Alla G. Bessmertnykh-Lemeune and Christine Stern and Roger Guilard},
title = {Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b03160},
number = {5},
pages = {3055--3070},
doi = {10.1021/acs.inorgchem.6b03160}
}
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MLA
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Enakieva, Yulia Yu., et al. “Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self-Assembly of meso-Porphyrinylphosphonic Acid Monoester.” Inorganic Chemistry, vol. 56, no. 5, Feb. 2017, pp. 3055-3070. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b03160.