Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.
Publication type: Journal Article
Publication date: 2017-05-09
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
28485931
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Inspired by the ongoing search for new superionic lithium thiophosphates for use in solid-state batteries, we present the synthesis and structural characterization of Li2P2S6, a novel crystalline lithium thiophosphate. Whereas M2P2S6 with the different alkaline elements (M = Na, K, Rb, Cs) is known, the lithium counterpart has not been reported yet. Herein, we present a combination of synchrotron pair distribution function analysis and neutron powder diffraction to elucidate the crystal structure and possible Li+ diffusion pathways of Li2P2S6. Additionally, impedance spectroscopy is used to evaluate its ionic conductivity. We show that Li2P2S6 possesses P2S62- polyhedral units with edge-sharing PS4 tetrahedra and only one-dimensional diffusion pathways with localized Li-Li pairs, leading to a low ionic conductivity for lithium.
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Dietrich C. et al. Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6. // Inorganic Chemistry. 2017. Vol. 56. No. 11. pp. 6681-6687.
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Dietrich C., Weber D. A., Culver S. P., Senyshyn A., Janek J., Zeier W. G. Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6. // Inorganic Chemistry. 2017. Vol. 56. No. 11. pp. 6681-6687.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b00751
UR - https://doi.org/10.1021/acs.inorgchem.7b00751
TI - Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.
T2 - Inorganic Chemistry
AU - Dietrich, Christian
AU - Weber, Dominik A.
AU - Culver, Sean P
AU - Senyshyn, A.
AU - Janek, Jürgen
AU - Zeier, Wolfgang G.
PY - 2017
DA - 2017/05/09
PB - American Chemical Society (ACS)
SP - 6681-6687
IS - 11
VL - 56
PMID - 28485931
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2017_Dietrich,
author = {Christian Dietrich and Dominik A. Weber and Sean P Culver and A. Senyshyn and Jürgen Janek and Wolfgang G. Zeier},
title = {Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6.},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.inorgchem.7b00751},
number = {11},
pages = {6681--6687},
doi = {10.1021/acs.inorgchem.7b00751}
}
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MLA
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Dietrich, Christian, et al. “Synthesis, Structural Characterization, and Lithium Ion Conductivity of the Lithium Thiophosphate Li2P2S6..” Inorganic Chemistry, vol. 56, no. 11, May. 2017, pp. 6681-6687. https://doi.org/10.1021/acs.inorgchem.7b00751.