Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data
Тип публикации: Journal Article
Дата публикации: 2017-10-20
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29052981
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The supramolecular dimeric complex [(μ-oxo)bis(tetra-15-crown-5-phthalocyaninato)(nicotinato)aluminum(III)]tetra(rubidium) bis(nicotinate) was prepared by addition of an excess of a methanol solution of rubidium nicotinate to a chloroform solution of the aluminum crown-phthalocyaninate, [(HO)Al(15C5)4Pc]. A single-crystal X-ray diffraction study of {[Rb4(NicAl(15C5)4Pc)2(μ-O)]2+(Nic-)2}·2.36HNic·11H2O demonstrated that two molecules of the aluminum crown-phthalocyaninate nicotinate are connected through an Al-O-Al bridge supported by sandwiching of crown ether moieties by Rb+ cations.
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Lapkina L. A. et al. Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data // Inorganic Chemistry. 2017. Vol. 57. No. 1. pp. 82-85.
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Lapkina L. A., LARCHENKO V. E., Kirakosyan G., Kirakosyan G. A., Tsivadze A., Tsivadze A. Y., Troyanov S., Gorbunova Y. G. Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data // Inorganic Chemistry. 2017. Vol. 57. No. 1. pp. 82-85.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b01983
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01983
TI - Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data
T2 - Inorganic Chemistry
AU - Lapkina, Lyudmila A.
AU - LARCHENKO, VLADIMIR E.
AU - Kirakosyan, Gayane
AU - Kirakosyan, Gayane A.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
AU - Troyanov, Sergey
AU - Gorbunova, Yulia G.
PY - 2017
DA - 2017/10/20
PB - American Chemical Society (ACS)
SP - 82-85
IS - 1
VL - 57
PMID - 29052981
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_Lapkina,
author = {Lyudmila A. Lapkina and VLADIMIR E. LARCHENKO and Gayane Kirakosyan and Gayane A. Kirakosyan and Aslan Tsivadze and Aslan Yu. Tsivadze and Sergey Troyanov and Yulia G. Gorbunova},
title = {Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data},
journal = {Inorganic Chemistry},
year = {2017},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01983},
number = {1},
pages = {82--85},
doi = {10.1021/acs.inorgchem.7b01983}
}
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Lapkina, Lyudmila A., et al. “Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data.” Inorganic Chemistry, vol. 57, no. 1, Oct. 2017, pp. 82-85. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01983.
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