Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation
Тип публикации: Journal Article
Дата публикации: 2017-10-13
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29027796
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Synthesis, structures, and magnetic properties of α-butoxy-substituted phthalocyaninato double-decker complexes Tb(α-obPc)2 (1-) (α-obPc: dianion of 1,4,8,11,15,18,22,25-octa(n-butoxy)phthalocyaninato) with protonated (1H), deprotonated (1[HDBU]), and diprotonated forms (1H2+) are discussed. X-ray analysis was used to confirm the position of the proton in 1H, and it was revealed that the protonation induced asymmetric distortion in 1H. In contrast, 1[HDBU] was distorted in a highly symmetric windmill-like fashion. 1H is arranged in a slipped column array in the crystal packing, whereas 1[HDBU] is arranged in a one-dimensional fashion, in which the magnetic easy axes of 1[HDBU] lie along the same line. From direct-current (dc) magnetic measurements, ferromagnetic Tb-Tb interactions occur in both 1H and 1[HDBU], and magnetic hysteresis was observed. However, the area of the magnetic hysteresis in 1[HDBU] is larger than that in 1H, meaning that magnetic relaxation time (τ) is longer in 1[HDBU]. In addition, the results of alternating-current magnetic measurements in a zero dc magnetic field indicate that τ of 1[HDBU] is longer as compared to 1H. In other words, protonation/deprotonation affects not only the molecular structures and crystal packing but also the single-molecule magnet properties.
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HORII Y. et al. Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation // Inorganic Chemistry. 2017. Vol. 57. No. 2. pp. 565-574.
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HORII Y., HORIE Y., KATOH K., Breedlove B. K., Yamashita M. Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation // Inorganic Chemistry. 2017. Vol. 57. No. 2. pp. 565-574.
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02124
UR - https://doi.org/10.1021/acs.inorgchem.7b02124
TI - Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation
T2 - Inorganic Chemistry
AU - HORII, Yoji
AU - HORIE, Yusuke
AU - KATOH, Keiichi
AU - Breedlove, Brian K
AU - Yamashita, M.
PY - 2017
DA - 2017/10/13
PB - American Chemical Society (ACS)
SP - 565-574
IS - 2
VL - 57
PMID - 29027796
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2017_HORII,
author = {Yoji HORII and Yusuke HORIE and Keiichi KATOH and Brian K Breedlove and M. Yamashita},
title = {Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation},
journal = {Inorganic Chemistry},
year = {2017},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.7b02124},
number = {2},
pages = {565--574},
doi = {10.1021/acs.inorgchem.7b02124}
}
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HORII, Yoji, et al. “Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation.” Inorganic Chemistry, vol. 57, no. 2, Oct. 2017, pp. 565-574. https://doi.org/10.1021/acs.inorgchem.7b02124.