A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance
Li-Li Fan
1
,
Yutong Wang
1
,
Zhenyu Xiao
1
,
Liangliang Zhang
1
,
Yaqiong Gong
2
,
Fang-Na Dai
1
,
Rongming Wang
1
,
Publication type: Journal Article
Publication date: 2017-10-30
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
29083917
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An amino-functionalized doubly interpenetrated microporous zinc metal-organic framework (UPC-30) has been solvothermally synthesized. UPC-30 can be stable at 190 °C and confirmed by powder X-ray diffraction. Gas adsorption measurements indicate that UPC-30 exhibits high H2 adsorption heat and CO2/CH4 separation efficiency. After the exchange of Me2NH2+ by Li+ in the channels, the H2 adsorption heat increased by 19.7%. Because of the existence of -NH2 groups in the channels, UPC-30 can effectively catalyze Knoevenagel condensation reactions with high yield and pore-size-dependent selectivity.
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35
Total citations:
35
Citations from 2024:
6
(17%)
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GOST
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Fan L. et al. A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance // Inorganic Chemistry. 2017. Vol. 56. No. 22. pp. 13634-13637.
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Fan L., Wang Y., Xiao Z., Zhang L., Gong Y., Dai F., Wang R., Sun D. A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance // Inorganic Chemistry. 2017. Vol. 56. No. 22. pp. 13634-13637.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.7b02148
UR - https://doi.org/10.1021/acs.inorgchem.7b02148
TI - A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance
T2 - Inorganic Chemistry
AU - Fan, Li-Li
AU - Wang, Yutong
AU - Xiao, Zhenyu
AU - Zhang, Liangliang
AU - Gong, Yaqiong
AU - Dai, Fang-Na
AU - Wang, Rongming
AU - Sun, Dao-Feng
PY - 2017
DA - 2017/10/30
PB - American Chemical Society (ACS)
SP - 13634-13637
IS - 22
VL - 56
PMID - 29083917
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
Copy
@article{2017_Fan,
author = {Li-Li Fan and Yutong Wang and Zhenyu Xiao and Liangliang Zhang and Yaqiong Gong and Fang-Na Dai and Rongming Wang and Dao-Feng Sun},
title = {A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance},
journal = {Inorganic Chemistry},
year = {2017},
volume = {56},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.inorgchem.7b02148},
number = {22},
pages = {13634--13637},
doi = {10.1021/acs.inorgchem.7b02148}
}
Cite this
MLA
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Fan, Li-Li, et al. “A Stable Amino-Functionalized Interpenetrated Metal–Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance.” Inorganic Chemistry, vol. 56, no. 22, Oct. 2017, pp. 13634-13637. https://doi.org/10.1021/acs.inorgchem.7b02148.
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