том 58 издание 2 страницы 1048-1057

The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence.

Igor A Litvinov 1
Tatiana P Gerasimova 1
Elvira Musina 1
Тип публикацииJournal Article
Дата публикации2019-01-02
scimago Q1
wos Q1
БС1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The unique L2Cu6I6 complexes containing two Cu3I3 units have been obtained via reaction of 1,5-diaza-3,7-diphosphacyclooctanes bearing ethylpyridyl substituents at phosphorus atoms with an excess of copper iodide. The structure of one of the complexes was confirmed by X-ray diffraction. It was shown that the complexes can exist in two crystalline phases with different parameters of the unit cell, which were detected by the PXRD data analyses. The solvent-free crystalline phases of the complexes display rare solid-state white emission at room temperature, which is observed due to the presence of two broad bands in the emission spectra with maxima at 464 and 610 nm. Quantum chemical computations show that the high-energy band has 3(M+X)LCT origin, whereas the low-energy band is interpreted as 3CC. The quantum yields of white luminescence of complexes reach 15-20%.
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Strelnik I. D. et al. The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. // Inorganic Chemistry. 2019. Vol. 58. No. 2. pp. 1048-1057.
ГОСТ со всеми авторами (до 50) Скопировать
Strelnik I. D., Dayanova I. R., Kolesnikov I. E., Fayzullin R. А., Litvinov I. A., Litvinov I. A., Samigullina A. I., Gerasimova T. I., Gerasimova T. P., Katsyuba S. A., Musina E., Karasik A. A. The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence. // Inorganic Chemistry. 2019. Vol. 58. No. 2. pp. 1048-1057.
RIS |
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TY - JOUR
DO - 10.1021/acs.inorgchem.8b01862
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01862
TI - The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence.
T2 - Inorganic Chemistry
AU - Strelnik, Igor D
AU - Dayanova, Irina R
AU - Kolesnikov, Ilya E.
AU - Fayzullin, R. А.
AU - Litvinov, I. A.
AU - Litvinov, Igor A
AU - Samigullina, Aida I.
AU - Gerasimova, Tatiana I.
AU - Gerasimova, Tatiana P
AU - Katsyuba, Sergey A.
AU - Musina, Elvira
AU - Karasik, Andrey A
PY - 2019
DA - 2019/01/02
PB - American Chemical Society (ACS)
SP - 1048-1057
IS - 2
VL - 58
PMID - 30601648
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2019_Strelnik,
author = {Igor D Strelnik and Irina R Dayanova and Ilya E. Kolesnikov and R. А. Fayzullin and I. A. Litvinov and Igor A Litvinov and Aida I. Samigullina and Tatiana I. Gerasimova and Tatiana P Gerasimova and Sergey A. Katsyuba and Elvira Musina and Andrey A Karasik},
title = {The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence.},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01862},
number = {2},
pages = {1048--1057},
doi = {10.1021/acs.inorgchem.8b01862}
}
MLA
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Strelnik, Igor D., et al. “The Assembly of Unique Hexanuclear Copper(I) Complexes with Effective White Luminescence..” Inorganic Chemistry, vol. 58, no. 2, Jan. 2019, pp. 1048-1057. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01862.