Inorganic Chemistry

, volume 58 , issue 9 , pages 5393-5396

Stable C₉₂(26) and C₉₂(38) as Well as Unstable C₉₂(50) and C₉₂(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C₉₂ Fullerene

Runnan Guan ¹

Fei Jin ¹

Shangfeng Yang ¹

Nadezhda B Tamm ²

Sergey Troyanov ²

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Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China |

Chemistry Department, Moscow State University, Leninskie gory, Moscow 119991, Russia |

Publication type: Journal Article

Publication date: 2019-04-05

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.9b00144

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PubMed ID: 30950266

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

High-temperature chlorination of C92 fractions, followed by single-crystal X-ray diffraction, resulted in the structure determination of C92(38)Cl18, C92(38)Cl22, C92(26)Cl24, nonclassical C90( NC)Cl22, and non-isolated-pentagon-rule C90Cl26. Two latter chloro derivatives were obtained by chlorination-promoted cage transformations via a single C2 loss from C92(50) and a combination of a C2 loss from C92(23) and three Stone-Wales rearrangements. The chlorination patterns are stabilized by the formation of isolated C═C bonds and aromatic substructures on carbon cages. The presence of C92 isomer numbers 23, 26, and 50 in the arc-discharge fullerene soot has been confirmed for the first time.

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Khamatgalimov Ayrat

DSc in Chemistry

90 publications, 887 citations

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

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Guan R. et al. Stable C92(26) and C92(38) as Well as Unstable C92(50) and C92(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C92 Fullerene // Inorganic Chemistry. 2019. Vol. 58. No. 9. pp. 5393-5396.

GOST all authors (up to 50) Copy

Guan R., Jin F., Yang S., Tamm N. B., Troyanov S. Stable C92(26) and C92(38) as Well as Unstable C92(50) and C92(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C92 Fullerene // Inorganic Chemistry. 2019. Vol. 58. No. 9. pp. 5393-5396.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.inorgchem.9b00144

UR - https://doi.org/10.1021/acs.inorgchem.9b00144

TI - Stable C92(26) and C92(38) as Well as Unstable C92(50) and C92(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C92 Fullerene

T2 - Inorganic Chemistry

AU - Guan, Runnan

AU - Jin, Fei

AU - Yang, Shangfeng

AU - Tamm, Nadezhda B

AU - Troyanov, Sergey

PY - 2019

DA - 2019/04/05

PB - American Chemical Society (ACS)

SP - 5393-5396

IS - 9

VL - 58

PMID - 30950266

SN - 0020-1669

SN - 1520-510X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Guan,

author = {Runnan Guan and Fei Jin and Shangfeng Yang and Nadezhda B Tamm and Sergey Troyanov},

title = {Stable C92(26) and C92(38) as Well as Unstable C92(50) and C92(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C92 Fullerene},

journal = {Inorganic Chemistry},

year = {2019},

volume = {58},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/acs.inorgchem.9b00144},

number = {9},

pages = {5393--5396},

doi = {10.1021/acs.inorgchem.9b00144}

}

MLA

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MLA Copy

Guan, Runnan, et al. “Stable C92(26) and C92(38) as Well as Unstable C92(50) and C92(23) Isolated-Pentagon-Rule Isomers As Revealed by Chlorination of C92 Fullerene.” Inorganic Chemistry, vol. 58, no. 9, Apr. 2019, pp. 5393-5396. https://doi.org/10.1021/acs.inorgchem.9b00144.

Publisher

American Chemical Society (ACS)

Journal

Inorganic Chemistry

scimago Q1

wos Q1

SJR

0.958

CiteScore

7.4

Impact factor

4.7

ISSN

00201669 (Print)

1520510X (Electronic)

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