Inorganic Chemistry

, том 58 , издание 15 , страницы 9562-9566

Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation

Rosa Diego ^{1, 2}

Alexander Pavlov ^{3, 4}

Mohanad Darawsheh ¹

Dmitry Aleshin ^{3, 5}

Joscha Nehrkorn ⁶

Yulia V. Nelyubina ^{3, 4}

Olivier Roubeau ⁷

Valentin V Novikov ^{3, 4}

Guillem Aromí ^{1, 2}

Скрыть аффилиации авторов Показать аффилиации авторов: 7 аффилиаций

Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain |

Institute of Nanoscience and Nanotechnology of the Unirvesity of Barcelona (IN2UB), Barcelona, Spain |

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova strasse 28, Moscow, Russia |

⁴

Moscow Institute of Physics and Technology, Institutskiy per. 9, Dolgoprudny, Moscow, Russia |

⁵

Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047 Moscow, Russia |

⁶

Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34−36, 45470 Mülheim an der Ruhr, Germany |

⁷

Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, 50009 Zaragoza, Spain

Университет Сарагосы

Институт нанонауки и материалов Арагона

Тип публикации: Journal Article

Дата публикации: 2019-07-08

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

БС1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.9b01334

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PubMed ID: 31283191

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The slow magnetic relaxation of CoII ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3]4+ and [CoZnL3]4+ coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic 1H NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously.

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Diego R. et al. Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation // Inorganic Chemistry. 2019. Vol. 58. No. 15. pp. 9562-9566.

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Diego R., Pavlov A., Darawsheh M., Aleshin D., Nehrkorn J., Nelyubina Y. V., Roubeau O., Novikov V. V., Aromí G. Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation // Inorganic Chemistry. 2019. Vol. 58. No. 15. pp. 9562-9566.

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TY - JOUR

DO - 10.1021/acs.inorgchem.9b01334

UR - https://doi.org/10.1021/acs.inorgchem.9b01334

TI - Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation

T2 - Inorganic Chemistry

AU - Diego, Rosa

AU - Pavlov, Alexander

AU - Darawsheh, Mohanad

AU - Aleshin, Dmitry

AU - Nehrkorn, Joscha

AU - Nelyubina, Yulia V.

AU - Roubeau, Olivier

AU - Novikov, Valentin V

AU - Aromí, Guillem

PY - 2019

DA - 2019/07/08

PB - American Chemical Society (ACS)

SP - 9562-9566

IS - 15

VL - 58

PMID - 31283191

SN - 0020-1669

SN - 1520-510X

ER -

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@article{2019_Diego,

author = {Rosa Diego and Alexander Pavlov and Mohanad Darawsheh and Dmitry Aleshin and Joscha Nehrkorn and Yulia V. Nelyubina and Olivier Roubeau and Valentin V Novikov and Guillem Aromí},

title = {Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation},

journal = {Inorganic Chemistry},

year = {2019},

volume = {58},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/acs.inorgchem.9b01334},

number = {15},

pages = {9562--9566},

doi = {10.1021/acs.inorgchem.9b01334}

}

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Diego, Rosa, et al. “Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation.” Inorganic Chemistry, vol. 58, no. 15, Jul. 2019, pp. 9562-9566. https://doi.org/10.1021/acs.inorgchem.9b01334.