volume 86 issue 10 pages 7163-7178

Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts

Nikita S Antonkin 1
Yulia A Vlasenko 1
Vladimir I Smirnov 2
Publication typeJournal Article
Publication date2021-05-04
scimago Q2
wos Q1
SJR0.737
CiteScore6.1
Impact factor3.6
ISSN00223263, 15206904
Organic Chemistry
Abstract
A novel approach to the preparation of imidazole-substituted cyclic iodonium salts has been developed via the oxidative cyclization of 1-phenyl-5-iodoimidazole using a cheap and available Oxone/H2SO4 oxidative system. The structure of the new polycyclic heteroarenes has been confirmed by single-crystal X-ray diffractometry, revealing the characteristic structure features for cyclic iodonium salts. The newly produced imidazole-flanked cyclic iodonium compounds were found to readily engage in a heterocyclization reaction with elemental sulfur, affording benzo[5,1-b]imidazothiazoles in good yields.
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GOST Copy
Antonkin N. S. et al. Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts // Journal of Organic Chemistry. 2021. Vol. 86. No. 10. pp. 7163-7178.
GOST all authors (up to 50) Copy
Antonkin N. S., Vlasenko Y. A., YOSHIMURA A., Smirnov V. I., Borodina T. N., Zhdankin V. V., S. Yusubov M., Shafir A., Postnikov P. S. Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts // Journal of Organic Chemistry. 2021. Vol. 86. No. 10. pp. 7163-7178.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.joc.1c00483
UR - https://doi.org/10.1021/acs.joc.1c00483
TI - Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts
T2 - Journal of Organic Chemistry
AU - Antonkin, Nikita S
AU - Vlasenko, Yulia A
AU - YOSHIMURA, Akira
AU - Smirnov, Vladimir I
AU - Borodina, Tatyana N
AU - Zhdankin, Viktor V.
AU - S. Yusubov, Mekhman
AU - Shafir, Alexandr
AU - Postnikov, Pavel S.
PY - 2021
DA - 2021/05/04
PB - American Chemical Society (ACS)
SP - 7163-7178
IS - 10
VL - 86
PMID - 33944564
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Antonkin,
author = {Nikita S Antonkin and Yulia A Vlasenko and Akira YOSHIMURA and Vladimir I Smirnov and Tatyana N Borodina and Viktor V. Zhdankin and Mekhman S. Yusubov and Alexandr Shafir and Pavel S. Postnikov},
title = {Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts},
journal = {Journal of Organic Chemistry},
year = {2021},
volume = {86},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.joc.1c00483},
number = {10},
pages = {7163--7178},
doi = {10.1021/acs.joc.1c00483}
}
MLA
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MLA Copy
Antonkin, Nikita S., et al. “Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts.” Journal of Organic Chemistry, vol. 86, no. 10, May. 2021, pp. 7163-7178. https://doi.org/10.1021/acs.joc.1c00483.