Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes
Publication type: Journal Article
Publication date: 2021-12-15
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
34908424
Organic Chemistry
Abstract
A series of triazole-cyanostilbene receptors were designed and synthesized. The receptor binds with the anions through various CH···anion hydrogen bonding interactions, where strong binding was observed for SO42- anions followed by Cl-, Br-, NO3-, and I-, calculated from the 1H NMR titration experiment. The NOESY NMR experiment of the receptor confirmed the formation of anion-induced folded conformation. The CH···anion hydrogen bonding interaction-mediated anion recognition and foldamer formation were further confirmed from geometry optimization studies of the anion-bound complex. The receptor transports Cl- anions efficiently compared to SO42- anions across the lipid bilayer membrane via a mobile carrier mechanism.
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Total citations:
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Citations from 2024:
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(55.17%)
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GOST
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Mondal D. et al. Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes // Journal of Organic Chemistry. 2021. Vol. 87. No. 1. pp. 10-17.
GOST all authors (up to 50)
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Mondal D., Ahmad M., Panwaria P., Upadhyay A., Talukdar P. Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes // Journal of Organic Chemistry. 2021. Vol. 87. No. 1. pp. 10-17.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.joc.1c01408
UR - https://doi.org/10.1021/acs.joc.1c01408
TI - Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes
T2 - Journal of Organic Chemistry
AU - Mondal, Debashis
AU - Ahmad, Manzoor
AU - Panwaria, Prakash
AU - Upadhyay, Avisikta
AU - Talukdar, Pinaki
PY - 2021
DA - 2021/12/15
PB - American Chemical Society (ACS)
SP - 10-17
IS - 1
VL - 87
PMID - 34908424
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Mondal,
author = {Debashis Mondal and Manzoor Ahmad and Prakash Panwaria and Avisikta Upadhyay and Pinaki Talukdar},
title = {Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes},
journal = {Journal of Organic Chemistry},
year = {2021},
volume = {87},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.joc.1c01408},
number = {1},
pages = {10--17},
doi = {10.1021/acs.joc.1c01408}
}
Cite this
MLA
Copy
Mondal, Debashis, et al. “Anion Recognition through Multivalent C–H Hydrogen Bonds: Anion-Induced Foldamer Formation and Transport across Phospholipid Membranes.” Journal of Organic Chemistry, vol. 87, no. 1, Dec. 2021, pp. 10-17. https://doi.org/10.1021/acs.joc.1c01408.