Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates
Publication type: Journal Article
Publication date: 2017-12-11
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
29178788
Organic Chemistry
Abstract
A cross-coupling of acyl chlorides with gem-difluorinated organozinc reagents affording difluorinated ketones is described. In the reaction, acyl chlorides are first treated with potassium dithiocarbamate to generate S-acyl dithiocarbamates, which couple with organozincs in the presence of a copper(I) catalyst.
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25
Total citations:
25
Citations from 2024:
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(32%)
Cite this
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MLA
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GOST
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Ashirbaev S. S. et al. Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates // Journal of Organic Chemistry. 2017. Vol. 83. No. 1. pp. 478-483.
GOST all authors (up to 50)
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Ashirbaev S. S., Levin V. V., Struchkova M. I., Dilman A. D. Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates // Journal of Organic Chemistry. 2017. Vol. 83. No. 1. pp. 478-483.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.joc.7b02598
UR - https://doi.org/10.1021/acs.joc.7b02598
TI - Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates
T2 - Journal of Organic Chemistry
AU - Ashirbaev, Salavat S
AU - Levin, Vitalij V
AU - Struchkova, Marina I.
AU - Dilman, Alexander D
PY - 2017
DA - 2017/12/11
PB - American Chemical Society (ACS)
SP - 478-483
IS - 1
VL - 83
PMID - 29178788
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Ashirbaev,
author = {Salavat S Ashirbaev and Vitalij V Levin and Marina I. Struchkova and Alexander D Dilman},
title = {Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates},
journal = {Journal of Organic Chemistry},
year = {2017},
volume = {83},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.joc.7b02598},
number = {1},
pages = {478--483},
doi = {10.1021/acs.joc.7b02598}
}
Cite this
MLA
Copy
Ashirbaev, Salavat S., et al. “Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates.” Journal of Organic Chemistry, vol. 83, no. 1, Dec. 2017, pp. 478-483. https://doi.org/10.1021/acs.joc.7b02598.
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