Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach
Publication type: Journal Article
Publication date: 2019-08-22
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
31436097
Organic Chemistry
Abstract
Transition-metal-catalyzed C-H activation synthesis of heterocyclic spiro[4,4]nonanes has persistently witnessed the use of additional stoichiometric transition-metal oxidant when employing C═C bond as the spiro ring closure site. Herein, we have addressed the issue by reporting a redox-neutral strategy for spiro[indene-1,4'-oxa-zolidinones] synthesis via Rh(III)-catalyzed coupling of 4-phenyl-1,3-oxazol-2(3H)-ones with alkynes. The synthesis features a broad substrate scope and high regiospecificity.
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7
Total citations:
7
Citations from 2024:
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(14.29%)
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GOST
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Liu Z. et al. Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach // Journal of Organic Chemistry. 2019. Vol. 84. No. 18. pp. 11945-11957.
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Liu Z., Zhang W., Guo S., Zhu J. Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach // Journal of Organic Chemistry. 2019. Vol. 84. No. 18. pp. 11945-11957.
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TY - JOUR
DO - 10.1021/acs.joc.9b01804
UR - https://doi.org/10.1021/acs.joc.9b01804
TI - Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach
T2 - Journal of Organic Chemistry
AU - Liu, Zhongsu
AU - Zhang, Wenjing
AU - Guo, Shan
AU - Zhu, Jin
PY - 2019
DA - 2019/08/22
PB - American Chemical Society (ACS)
SP - 11945-11957
IS - 18
VL - 84
PMID - 31436097
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2019_Liu,
author = {Zhongsu Liu and Wenjing Zhang and Shan Guo and Jin Zhu},
title = {Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach},
journal = {Journal of Organic Chemistry},
year = {2019},
volume = {84},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.joc.9b01804},
number = {18},
pages = {11945--11957},
doi = {10.1021/acs.joc.9b01804}
}
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MLA
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Liu, Zhongsu, et al. “Spiro[indene-1,4′-oxa-zolidinones] Synthesis via Rh(III)-Catalyzed Coupling of 4-Phenyl-1,3-oxazol-2(3H)-ones with Alkynes: A Redox-Neutral Approach.” Journal of Organic Chemistry, vol. 84, no. 18, Aug. 2019, pp. 11945-11957. https://doi.org/10.1021/acs.joc.9b01804.