Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones
Publication type: Journal Article
Publication date: 2019-09-20
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
31538480
Organic Chemistry
Abstract
A Pd-catalyzed ring-opening sulfonylation of gem-difluorocyclopropanes is reported. This protocol involves C-C bond cleavage, β-F elimination, and allylic coupling to form corresponding 2-fluoroallylic sulfones efficiently with Z-selectivity. Different substrates bearing diverse functional groups are tolerated. Moreover, this method is successfully used for the late-stage derivation of several bioactive molecules.
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64
Total citations:
64
Citations from 2025:
7
(10.94%)
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GOST
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Ni J. et al. Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones // Journal of Organic Chemistry. 2019. Vol. 84. No. 21. pp. 13646-13654.
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Ni J., Nishonov B., Pardaev A., Zhang A. Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones // Journal of Organic Chemistry. 2019. Vol. 84. No. 21. pp. 13646-13654.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.joc.9b01897
UR - https://doi.org/10.1021/acs.joc.9b01897
TI - Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones
T2 - Journal of Organic Chemistry
AU - Ni, Jiabin
AU - Nishonov, Bekzod
AU - Pardaev, Azizbek
AU - Zhang, Ao
PY - 2019
DA - 2019/09/20
PB - American Chemical Society (ACS)
SP - 13646-13654
IS - 21
VL - 84
PMID - 31538480
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Ni,
author = {Jiabin Ni and Bekzod Nishonov and Azizbek Pardaev and Ao Zhang},
title = {Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones},
journal = {Journal of Organic Chemistry},
year = {2019},
volume = {84},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.joc.9b01897},
number = {21},
pages = {13646--13654},
doi = {10.1021/acs.joc.9b01897}
}
Cite this
MLA
Copy
Ni, Jiabin, et al. “Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones.” Journal of Organic Chemistry, vol. 84, no. 21, Sep. 2019, pp. 13646-13654. https://doi.org/10.1021/acs.joc.9b01897.