Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study
Publication type: Journal Article
Publication date: 2019-02-11
scimago Q2
wos Q2
SJR: 0.634
CiteScore: 4.8
Impact factor: 2.8
ISSN: 10895639, 15205215
PubMed ID:
30741541
Physical and Theoretical Chemistry
Abstract
The research on heteroaromatic azoswitches has been blossoming in recent years due to their astonishingly broad range of properties. Minimal chemical modifications can drastically change the demeanor of these switches, regarding photophysical and (photo)chemical properties, promoting them as ideal scaffolds for a vast variety of applications based on bistable light-addressable systems. However, most of the characteristics exhibited by heteroaryl azoswitches were found empirically, and only a few works focus on their rationalization. Herein we report on a mechanistic study employing phenylazoindoles as a model reference, combining spectroscopic experiments with comprehensive computational analysis. This approach will elucidate the intrinsic correlations between the molecular structure of the switch and its thermal behavior, allowing a more rational design transferable to various heteroaryl azoswitches.
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51
Total citations:
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Citations from 2024:
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(45%)
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GOST
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Crespi S. et al. Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study // Journal of Physical Chemistry A. 2019. Vol. 123. No. 9. pp. 1814-1823.
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Crespi S., Simeth N. A., Bellisario A., Fagnoni M., König B. Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study // Journal of Physical Chemistry A. 2019. Vol. 123. No. 9. pp. 1814-1823.
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RIS
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TY - JOUR
DO - 10.1021/acs.jpca.8b11734
UR - https://doi.org/10.1021/acs.jpca.8b11734
TI - Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study
T2 - Journal of Physical Chemistry A
AU - Crespi, Stefano
AU - Simeth, Nadja A
AU - Bellisario, Alfredo
AU - Fagnoni, Maurizio
AU - König, Burkhard
PY - 2019
DA - 2019/02/11
PB - American Chemical Society (ACS)
SP - 1814-1823
IS - 9
VL - 123
PMID - 30741541
SN - 1089-5639
SN - 1520-5215
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Crespi,
author = {Stefano Crespi and Nadja A Simeth and Alfredo Bellisario and Maurizio Fagnoni and Burkhard König},
title = {Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study},
journal = {Journal of Physical Chemistry A},
year = {2019},
volume = {123},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.jpca.8b11734},
number = {9},
pages = {1814--1823},
doi = {10.1021/acs.jpca.8b11734}
}
Cite this
MLA
Copy
Crespi, Stefano, et al. “Unraveling the Thermal Isomerization Mechanisms of Heteroaryl Azoswitches: Phenylazoindoles as Case Study.” Journal of Physical Chemistry A, vol. 123, no. 9, Feb. 2019, pp. 1814-1823. https://doi.org/10.1021/acs.jpca.8b11734.