Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy
Тип публикации: Journal Article
Дата публикации: 2017-10-12
SCImago Q1
WOS Q3
БС1
SJR: 0.82
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Краткое описание
Multinuclear solid-state nuclear magnetic resonance spectroscopy was used in combination with Mossbauer spectroscopy and synchrotron diffraction to investigate the local and long-range structure as well as the Li-ion dynamics in a Li10SnP2S12-based composite. Although two additional phases could be detected (Li7PS6 and Li4SnS4), the Li ion dynamics turn out to be very fast with a Li diffusion coefficient of 1.6 × 10–12 m2/s, a Li+ ion conductivity of ∼2 mS/cm (both at 303 K), and a small activation barrier of 0.13 eV for single Li+ ion jumps.
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ГОСТ
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Kaus M. et al. Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy // Journal of Physical Chemistry C. 2017. Vol. 121. No. 42. pp. 23370-23376.
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Kaus M., Stöffler H., Yavuz M., Zinkevich T., Knapp M., Ehrenberg H., Indris S. Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy // Journal of Physical Chemistry C. 2017. Vol. 121. No. 42. pp. 23370-23376.
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TY - JOUR
DO - 10.1021/acs.jpcc.7b08350
UR - https://doi.org/10.1021/acs.jpcc.7b08350
TI - Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy
T2 - Journal of Physical Chemistry C
AU - Kaus, Maximilian
AU - Stöffler, Heike
AU - Yavuz, Murat
AU - Zinkevich, Tatiana
AU - Knapp, Michael
AU - Ehrenberg, H.
AU - Indris, Sylvio
PY - 2017
DA - 2017/10/12
PB - American Chemical Society (ACS)
SP - 23370-23376
IS - 42
VL - 121
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2017_Kaus,
author = {Maximilian Kaus and Heike Stöffler and Murat Yavuz and Tatiana Zinkevich and Michael Knapp and H. Ehrenberg and Sylvio Indris},
title = {Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy},
journal = {Journal of Physical Chemistry C},
year = {2017},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.jpcc.7b08350},
number = {42},
pages = {23370--23376},
doi = {10.1021/acs.jpcc.7b08350}
}
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MLA
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Kaus, Maximilian, et al. “Local Structures and Li Ion Dynamics in a Li10SnP2S12-Based Composite Observed by Multinuclear Solid-State NMR Spectroscopy.” Journal of Physical Chemistry C, vol. 121, no. 42, Oct. 2017, pp. 23370-23376. https://doi.org/10.1021/acs.jpcc.7b08350.
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