volume 123 issue 37 pages 23167-23176

Size Effects in Nanocrystalline Thoria

Daria V Likhosherstova 1
Tatiana B. Shatalova 1
Kristina O. Kvashnina 4, 5
Publication typeJournal Article
Publication date2019-08-26
scimago Q1
wos Q3
SJR0.914
CiteScore6.2
Impact factor3.2
ISSN19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
The facile chemical precipitation method and subsequent thermal treatment were shown to be suitable for preparation of crystalline ThO2 nanoparticles (NPs) in a wide range of particle sizes (from 2.5 to 34.3 nm). The obtained NPs were investigated with X-ray diffraction, high-resolution transmission electron microscopy, and X-ray absorption techniques to find out the possible size effects associated with nanocrystalline thoria. For 2.5 nm NPs, the lattice parameter of ThO2 was found to increase by up to 1.1%, in comparison with the bulk material. The decrease in the particle size was also accompanied by a significant decrease in the Th–Th coordination number.
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GOST Copy
Plakhova T. V. et al. Size Effects in Nanocrystalline Thoria // Journal of Physical Chemistry C. 2019. Vol. 123. No. 37. pp. 23167-23176.
GOST all authors (up to 50) Copy
Plakhova T. V., Romanchuk A., Likhosherstova D. V., Baranchikov A. E., Dorovatovskii P., Svetogorov R., Shatalova T. B., Egorova T. B., Trigub A. L., Kvashnina K., Kvashnina K. O., Ivanov V. K., Kalmykov S. N. Size Effects in Nanocrystalline Thoria // Journal of Physical Chemistry C. 2019. Vol. 123. No. 37. pp. 23167-23176.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.jpcc.9b04379
UR - https://pubs.acs.org/doi/10.1021/acs.jpcc.9b04379
TI - Size Effects in Nanocrystalline Thoria
T2 - Journal of Physical Chemistry C
AU - Plakhova, Tatiana V
AU - Romanchuk, Anna
AU - Likhosherstova, Daria V
AU - Baranchikov, Alexander E
AU - Dorovatovskii, Pavel
AU - Svetogorov, Roman
AU - Shatalova, Tatiana B.
AU - Egorova, Tolganay B
AU - Trigub, Alexander L.
AU - Kvashnina, Kristina
AU - Kvashnina, Kristina O.
AU - Ivanov, Vladimir K.
AU - Kalmykov, Stepan N.
PY - 2019
DA - 2019/08/26
PB - American Chemical Society (ACS)
SP - 23167-23176
IS - 37
VL - 123
SN - 1932-7447
SN - 1932-7455
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Plakhova,
author = {Tatiana V Plakhova and Anna Romanchuk and Daria V Likhosherstova and Alexander E Baranchikov and Pavel Dorovatovskii and Roman Svetogorov and Tatiana B. Shatalova and Tolganay B Egorova and Alexander L. Trigub and Kristina Kvashnina and Kristina O. Kvashnina and Vladimir K. Ivanov and Stepan N. Kalmykov},
title = {Size Effects in Nanocrystalline Thoria},
journal = {Journal of Physical Chemistry C},
year = {2019},
volume = {123},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://pubs.acs.org/doi/10.1021/acs.jpcc.9b04379},
number = {37},
pages = {23167--23176},
doi = {10.1021/acs.jpcc.9b04379}
}
MLA
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MLA Copy
Plakhova, Tatiana V., et al. “Size Effects in Nanocrystalline Thoria.” Journal of Physical Chemistry C, vol. 123, no. 37, Aug. 2019, pp. 23167-23176. https://pubs.acs.org/doi/10.1021/acs.jpcc.9b04379.