Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers
Ilya E. Kolesnikov
2, 3
,
Igor D Strelnik
1
,
Elvira Musina
1
,
E. Lähderanta
3
,
Andrey A Karasik
1
,
1
3
LUT University, Skinnarilankatu 34, 53850 Lappeenranta, Finland
|
Тип публикации: Journal Article
Дата публикации: 2019-09-29
scimago Q1
wos Q3
БС1
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Краткое описание
For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
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Shamsieva A. V. et al. Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers // Journal of Physical Chemistry C. 2019. Vol. 123. No. 42. pp. 25863-25870.
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Shamsieva A. V., Kolesnikov I. E., Strelnik I. D., Gerasimova T. I., Kalinichev A. A., Katsyuba S. A., Musina E., Lähderanta E., Karasik A. A., Sinyashin O. G. Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers // Journal of Physical Chemistry C. 2019. Vol. 123. No. 42. pp. 25863-25870.
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TY - JOUR
DO - 10.1021/acs.jpcc.9b07603
UR - https://doi.org/10.1021/acs.jpcc.9b07603
TI - Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers
T2 - Journal of Physical Chemistry C
AU - Shamsieva, Aliia V
AU - Kolesnikov, Ilya E.
AU - Strelnik, Igor D
AU - Gerasimova, Tatiana I.
AU - Kalinichev, Alexey A
AU - Katsyuba, Sergey A.
AU - Musina, Elvira
AU - Lähderanta, E.
AU - Karasik, Andrey A
AU - Sinyashin, Oleg G.
PY - 2019
DA - 2019/09/29
PB - American Chemical Society (ACS)
SP - 25863-25870
IS - 42
VL - 123
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2019_Shamsieva,
author = {Aliia V Shamsieva and Ilya E. Kolesnikov and Igor D Strelnik and Tatiana I. Gerasimova and Alexey A Kalinichev and Sergey A. Katsyuba and Elvira Musina and E. Lähderanta and Andrey A Karasik and Oleg G. Sinyashin},
title = {Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers},
journal = {Journal of Physical Chemistry C},
year = {2019},
volume = {123},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.jpcc.9b07603},
number = {42},
pages = {25863--25870},
doi = {10.1021/acs.jpcc.9b07603}
}
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MLA
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Shamsieva, Aliia V., et al. “Fresh Look on the Nature of Dual-Band Emission of Octahedral Copper-Iodide Clusters—Promising Ratiometric Luminescent Thermometers.” Journal of Physical Chemistry C, vol. 123, no. 42, Sep. 2019, pp. 25863-25870. https://doi.org/10.1021/acs.jpcc.9b07603.