Langmuir, volume 34, issue 18, pages 5184-5192
Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful
Meshkov Ivan N
1
,
Shiryaev A. A.
1, 2
,
Ежов А. А.
4, 5
,
Nugmanova Alsu G
1, 6
,
Gorbunova Yulia G.
1, 3
,
Arslanov Vladimir V.
1
,
Publication type: Journal Article
Publication date: 2018-04-18
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
Porphyrin-based metal-organic frameworks on surfaces are a new class of planar materials with promising features for applications in chemical sensing, catalysis, and organic optoelectronics at nanoscale. Herein, we studied systematically a series of the SURMOFs assembled from variously meso-carboxyphenyl/pyridyl-substituted porphyrins and zinc acetate on template monolayers of graphene oxide via layer-by-layer deposition. This microscopically flat template can initiate the growth of macroscopically uniform SURMOF films exhibiting well-resolved X-ray diffraction. By applying the D'yakonov method, which has been previously used for the extraction of self-convolution of electron density in clay minerals, to the analysis of the experimental diffraction patterns of the SURMOFs, we determined the relation between the structure of porphyrin linkers and the geometry of packing motives in the films. We showed that the packing of the SURMOFs differs significantly from that of bulk powders of similar composition because of steric limitations imposed on the assembly in 2D space. The results of microscopic examination of the SURMOFs suggest that the type of metal-to-linker chemical bonding dictates the morphology of the films. Our method provides an enlightening picture of the interplay between supramolecular ordering and surface-directed assembly in porphyrin-based SURMOFs and is useful for rationalizing the fabrication of various classes of layered metal-organic frameworks on solids.
Citations by journals
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1
2
3
4
5
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Colloid Journal
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Colloid Journal
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Russian Chemical Reviews
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Advanced Functional Materials
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Applied Surface Science
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1 publication, 4.76%
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Langmuir
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Langmuir
1 publication, 4.76%
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Chemical Physics Reviews
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Chemical Physics Reviews
1 publication, 4.76%
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Journal of Porphyrins and Phthalocyanines
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Journal of Porphyrins and Phthalocyanines
1 publication, 4.76%
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Journal of Composites Science
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Journal of Composites Science
1 publication, 4.76%
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Surface Science
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Surface Science
1 publication, 4.76%
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EnergyChem
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EnergyChem
1 publication, 4.76%
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ChemistryOpen
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ChemistryOpen
1 publication, 4.76%
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Crystal Growth and Design
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Crystal Growth and Design
1 publication, 4.76%
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New Journal of Chemistry
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New Journal of Chemistry
1 publication, 4.76%
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ACS applied materials & interfaces
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ACS applied materials & interfaces
1 publication, 4.76%
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1
2
3
4
5
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Citations by publishers
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1
2
3
4
5
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Pleiades Publishing
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Pleiades Publishing
5 publications, 23.81%
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Elsevier
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Elsevier
3 publications, 14.29%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
3 publications, 14.29%
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Wiley
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Wiley
2 publications, 9.52%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 9.52%
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Thomas Telford
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Thomas Telford
1 publication, 4.76%
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 4.76%
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World Scientific
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World Scientific
1 publication, 4.76%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 4.76%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 4.76%
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1
2
3
4
5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Meshkov I. N. et al. Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful // Langmuir. 2018. Vol. 34. No. 18. pp. 5184-5192.
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Meshkov I. N., Zvyagina A. I., Shiryaev A. A., Baranchikov A. E., Ежов А. А., Nugmanova A. G., Enakieva Y. Y., Gorbunova Y. G., Arslanov V. V., Kalinina M. A. Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful // Langmuir. 2018. Vol. 34. No. 18. pp. 5184-5192.
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TY - JOUR
DO - 10.1021/acs.langmuir.7b04384
UR - https://doi.org/10.1021%2Facs.langmuir.7b04384
TI - Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful
T2 - Langmuir
AU - Nugmanova, Alsu G
AU - Arslanov, Vladimir V.
AU - Meshkov, Ivan N
AU - Zvyagina, Alexandra I
AU - Baranchikov, Alexander E
AU - Gorbunova, Yulia G.
AU - Kalinina, Maria A
AU - Shiryaev, A. A.
AU - Ежов, А. А.
AU - Enakieva, Yulia Yu.
PY - 2018
DA - 2018/04/18 00:00:00
PB - American Chemical Society (ACS)
SP - 5184-5192
IS - 18
VL - 34
SN - 0743-7463
SN - 1520-5827
ER -
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@article{2018_Meshkov,
author = {Alsu G Nugmanova and Vladimir V. Arslanov and Ivan N Meshkov and Alexandra I Zvyagina and Alexander E Baranchikov and Yulia G. Gorbunova and Maria A Kalinina and A. A. Shiryaev and А. А. Ежов and Yulia Yu. Enakieva},
title = {Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful},
journal = {Langmuir},
year = {2018},
volume = {34},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facs.langmuir.7b04384},
number = {18},
pages = {5184--5192},
doi = {10.1021/acs.langmuir.7b04384}
}
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Meshkov, Ivan N., et al. “Understanding Self-Assembly of Porphyrin-Based SURMOFs: How Layered Minerals Can Be Useful.” Langmuir, vol. 34, no. 18, Apr. 2018, pp. 5184-5192. https://doi.org/10.1021%2Facs.langmuir.7b04384.