ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control
Publication type: Journal Article
Publication date: 2017-03-24
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Atom transfer radical polymerization (ATRP) in water is characterized by very high catalytic activity, i.e. the rate constant (kact) of the “activation” reaction between CuI complexes and alkyl halides (RX) is very large. To accurately study such fast reactions in water, we developed a collection of electrochemical methods applicable for the determination of a vast range of kact values (>7 orders of magnitude). These included rate constants of extremely fast reactions with kact > 107 mol–1 dm3 s–1. We studied three widely used ATRP catalysts ([CuIPMDETA]+, [CuITPMA]+, and [CuIMe6TREN]+) and an extended series of water-soluble initiators. Accurate results were obtained in the range 1 < kact < 108 mol–1 dm3 s–1, allowing to build for the first time precise structure–reactivity correlations for aqueous ATRP, in both pure water and water/monomer mixtures. The results were compared to traditional ATRP systems in organic solvents. The collected data greatly expand the available range of investigated catalyst/in...
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104
Total citations:
104
Citations from 2024:
18
(17.31%)
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GOST
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Fantin M. et al. ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control // Macromolecules. 2017. Vol. 50. No. 7. pp. 2696-2705.
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Fantin M., Isse A. A., Matyjaszewski K., Gennaro A. ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control // Macromolecules. 2017. Vol. 50. No. 7. pp. 2696-2705.
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RIS
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TY - JOUR
DO - 10.1021/acs.macromol.7b00246
UR - https://doi.org/10.1021/acs.macromol.7b00246
TI - ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control
T2 - Macromolecules
AU - Fantin, Marco
AU - Isse, Abdirisak Ahmed
AU - Matyjaszewski, Krzysztof
AU - Gennaro, Armando
PY - 2017
DA - 2017/03/24
PB - American Chemical Society (ACS)
SP - 2696-2705
IS - 7
VL - 50
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Fantin,
author = {Marco Fantin and Abdirisak Ahmed Isse and Krzysztof Matyjaszewski and Armando Gennaro},
title = {ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control},
journal = {Macromolecules},
year = {2017},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.macromol.7b00246},
number = {7},
pages = {2696--2705},
doi = {10.1021/acs.macromol.7b00246}
}
Cite this
MLA
Copy
Fantin, Marco, et al. “ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control.” Macromolecules, vol. 50, no. 7, Mar. 2017, pp. 2696-2705. https://doi.org/10.1021/acs.macromol.7b00246.