Macromolecules, volume 51, issue 10, pages 3640-3646
A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction
Publication type: Journal Article
Publication date: 2018-05-02
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Construction of block copolymers is a practical method for modifying the properties of CO2-based polycarbonates (CO2-PCs) in order to meet specific needs. Herein, we report a well-defined single-site β-diiminate zinc complex 1 equipped with the capacities of coordination copolymerization of CO2/epoxide and reversible addition–fragmentation chain transfer (RAFT) polymerization of vinyl monomers. Complex 1 is specifically designed to possess a 3-(benzylthiocarbonothioylthio)propionate (BSTP) initiating group, which enables the controlled ring-opening copolymerization of epoxides and CO2, leaving a polycarbonate with BSTP functional group at the end of the chain. The end-capped BSTP allows direct chain extension via living RAFT polymerization, thus providing a robust method to construct various CO2-based block copolymers in one pot via a tandem catalysis strategy. The structure of 1 is established by single-crystal X-ray diffraction as well as 1H and 13C NMR. By utilizing 1, a wide range of CO2-based block c...
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Zhang Y., Yang G. W., Wu G. A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction // Macromolecules. 2018. Vol. 51. No. 10. pp. 3640-3646.
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Zhang Y., Yang G. W., Wu G. A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction // Macromolecules. 2018. Vol. 51. No. 10. pp. 3640-3646.
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TY - JOUR
DO - 10.1021/acs.macromol.8b00576
UR - https://doi.org/10.1021/acs.macromol.8b00576
TI - A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction
T2 - Macromolecules
AU - Zhang, Yaoyao
AU - Yang, Guan Wen
AU - Wu, Guangpeng
PY - 2018
DA - 2018/05/02
PB - American Chemical Society (ACS)
SP - 3640-3646
IS - 10
VL - 51
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2018_Zhang,
author = {Yaoyao Zhang and Guan Wen Yang and Guangpeng Wu},
title = {A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction},
journal = {Macromolecules},
year = {2018},
volume = {51},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.macromol.8b00576},
number = {10},
pages = {3640--3646},
doi = {10.1021/acs.macromol.8b00576}
}
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Zhang, Yaoyao, et al. “A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction.” Macromolecules, vol. 51, no. 10, May. 2018, pp. 3640-3646. https://doi.org/10.1021/acs.macromol.8b00576.