Macromolecules, volume 51, issue 14, pages 5346-5351
Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst
1
Department of Chemistry, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, U.K.
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Publication type: Journal Article
Publication date: 2018-07-11
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Well-defined pentablock copolymers are prepared using a single catalyst, in one pot, from four different monomers: anhydride, epoxide, lactone, and CO2. The dizinc catalyst bridges three distinct polymerization cycles and performs a double switch in polymerization mechanism to produce pentablock copolymers. The new materials are hydroxyl-telechelic and are efficiently postfunctionalized to introduce polar and nonpolar side-chains.
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Chen T. T. D., Zhu Y., Williams C. Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst // Macromolecules. 2018. Vol. 51. No. 14. pp. 5346-5351.
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Chen T. T. D., Zhu Y., Williams C. Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst // Macromolecules. 2018. Vol. 51. No. 14. pp. 5346-5351.
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TY - JOUR
DO - 10.1021/acs.macromol.8b01224
UR - https://doi.org/10.1021/acs.macromol.8b01224
TI - Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst
T2 - Macromolecules
AU - Chen, T. T. D.
AU - Zhu, Yunqing
AU - Williams, Charlotte
PY - 2018
DA - 2018/07/11
PB - American Chemical Society (ACS)
SP - 5346-5351
IS - 14
VL - 51
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2018_Chen,
author = {T. T. D. Chen and Yunqing Zhu and Charlotte Williams},
title = {Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst},
journal = {Macromolecules},
year = {2018},
volume = {51},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.macromol.8b01224},
number = {14},
pages = {5346--5351},
doi = {10.1021/acs.macromol.8b01224}
}
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Chen, T. T. D., et al. “Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst.” Macromolecules, vol. 51, no. 14, Jul. 2018, pp. 5346-5351. https://doi.org/10.1021/acs.macromol.8b01224.