Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
Publication type: Journal Article
Publication date: 2018-09-25
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond traditional polymer science has necessitated the development of alternative strategies for controlling polymer growth. Driven by applications that are sensitive to metal ion contamination, “greener” methodologies are emerging as a powerful alternative to conventional ATRP. Organic catalysis represents a major evolution of ATRP with metal-free systems holding significant potential as user-friendly methods for utility in biological and microelectronic applications. In addition, shifting from a combination of thermal activation/metal ions/ligands to simpler organic catalysis/light activation increases compatibility with functional monomers and allows the development of novel surface patterning strategies. Herein, we highlight key discoveries and recent developments in metal-free ATRP, while providing a perspective for future opportunities in this emerging area.
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198
Total citations:
198
Citations from 2024:
37
(18.69%)
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GOST
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Discekici E. H. et al. Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization // Macromolecules. 2018. Vol. 51. No. 19. pp. 7421-7434.
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Discekici E. H., Anastasaki A., Read De Alaniz J., Hawker C. J. Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization // Macromolecules. 2018. Vol. 51. No. 19. pp. 7421-7434.
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RIS
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TY - JOUR
DO - 10.1021/acs.macromol.8b01401
UR - https://doi.org/10.1021/acs.macromol.8b01401
TI - Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
T2 - Macromolecules
AU - Discekici, Emre H
AU - Anastasaki, Athina
AU - Read De Alaniz, J
AU - Hawker, C. J.
PY - 2018
DA - 2018/09/25
PB - American Chemical Society (ACS)
SP - 7421-7434
IS - 19
VL - 51
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Discekici,
author = {Emre H Discekici and Athina Anastasaki and J Read De Alaniz and C. J. Hawker},
title = {Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization},
journal = {Macromolecules},
year = {2018},
volume = {51},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.macromol.8b01401},
number = {19},
pages = {7421--7434},
doi = {10.1021/acs.macromol.8b01401}
}
Cite this
MLA
Copy
Discekici, Emre H., et al. “Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization.” Macromolecules, vol. 51, no. 19, Sep. 2018, pp. 7421-7434. https://doi.org/10.1021/acs.macromol.8b01401.