volume 21 issue 4 pages 655-659

Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions

Publication typeJournal Article
Publication date2017-03-27
scimago Q1
wos Q1
SJR0.865
CiteScore5.4
Impact factor3.5
ISSN10836160, 1520586X
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
A newly established in situ technique using Raman spectroscopy was employed for the detailed kinetic investigation of mechanochemical reaction pathways. This approach was applied for the systematic investigation of the direct influence of colliding balls on the reaction rate constants of a mechanochemical cocrystallization reaction. As a model reaction, the mechanochemical cocrystallization of felodipine and the coformer imidazole was investigated. Keeping the total ball mass constant by varying the number of milling balls, our study reveals that the impact of each single collision has a more significant influence on the reaction kinetics than expected.
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GOST |
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GOST Copy
Fischer F. et al. Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions // Organic Process Research and Development. 2017. Vol. 21. No. 4. pp. 655-659.
GOST all authors (up to 50) Copy
Fischer F., Fendel N., Greiser S., Rademann K., Emmerling F. Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions // Organic Process Research and Development. 2017. Vol. 21. No. 4. pp. 655-659.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.oprd.6b00435
UR - https://doi.org/10.1021/acs.oprd.6b00435
TI - Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions
T2 - Organic Process Research and Development
AU - Fischer, Franziska
AU - Fendel, Nicole
AU - Greiser, Sebastian
AU - Rademann, Klaus
AU - Emmerling, Franziska
PY - 2017
DA - 2017/03/27
PB - American Chemical Society (ACS)
SP - 655-659
IS - 4
VL - 21
SN - 1083-6160
SN - 1520-586X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Fischer,
author = {Franziska Fischer and Nicole Fendel and Sebastian Greiser and Klaus Rademann and Franziska Emmerling},
title = {Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions},
journal = {Organic Process Research and Development},
year = {2017},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.oprd.6b00435},
number = {4},
pages = {655--659},
doi = {10.1021/acs.oprd.6b00435}
}
MLA
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MLA Copy
Fischer, Franziska, et al. “Impact Is Important—Systematic Investigation of the Influence of Milling Balls in Mechanochemical Reactions.” Organic Process Research and Development, vol. 21, no. 4, Mar. 2017, pp. 655-659. https://doi.org/10.1021/acs.oprd.6b00435.