Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient
Eric C. Johnson
1
,
David Chavez
2
,
Rosario C. Sausa
3
,
Edward B. Byrd
3
,
Leah A. Wingard
1
,
Pablo E Guzmán
1
1
Energetics Technology Branch, U.S. Army Research Laboratory, Aberdeen Proving Ground, Maryland 21005, United States
|
2
3
Energetic Materials Science Branch, U.S. Army Research Laboratory, Aberdeen Proving Ground, Maryland 21005, United States
|
Publication type: Journal Article
Publication date: 2018-05-25
scimago Q1
wos Q1
SJR: 0.865
CiteScore: 5.4
Impact factor: 3.5
ISSN: 10836160, 1520586X
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Discussed herein is the synthesis of bis(1,2,4-oxadiazole)bis(methylene) dinitrate, determination of its crystal structure by X-ray diffractometry, calculations of its explosive performance, and sensitivity measurements. Steps taken to optimize the synthesis process and to improve yields of the dinitrate are also discussed. Bis(1,2,4-oxadiazole)bis(methylene) dinitrate has a calculated detonation pressure 50% higher than that of TNT. The dinitrate compound exhibits a relatively high decomposition temperature that is rarely observed for nitrate-based compounds. The dinitrate was found to have lower sensitivities to impact and friction compared with RDX. It is believed that intramolecular hydrogen bonding observed in the crystal lattice assists in the relatively high thermal stability and relatively low sensitivity of the material.
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Johnson E. C. et al. Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient // Organic Process Research and Development. 2018. Vol. 22. No. 6. pp. 736-740.
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Johnson E. C., Sabatini J. J., Chavez D., Sausa R. C., Byrd E. B., Wingard L. A., Guzmán P. E. Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient // Organic Process Research and Development. 2018. Vol. 22. No. 6. pp. 736-740.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.oprd.8b00076
UR - https://doi.org/10.1021/acs.oprd.8b00076
TI - Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient
T2 - Organic Process Research and Development
AU - Johnson, Eric C.
AU - Sabatini, Jesse J.
AU - Chavez, David
AU - Sausa, Rosario C.
AU - Byrd, Edward B.
AU - Wingard, Leah A.
AU - Guzmán, Pablo E
PY - 2018
DA - 2018/05/25
PB - American Chemical Society (ACS)
SP - 736-740
IS - 6
VL - 22
SN - 1083-6160
SN - 1520-586X
ER -
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@article{2018_Johnson,
author = {Eric C. Johnson and Jesse J. Sabatini and David Chavez and Rosario C. Sausa and Edward B. Byrd and Leah A. Wingard and Pablo E Guzmán},
title = {Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient},
journal = {Organic Process Research and Development},
year = {2018},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.oprd.8b00076},
number = {6},
pages = {736--740},
doi = {10.1021/acs.oprd.8b00076}
}
Cite this
MLA
Copy
Johnson, Eric C., et al. “Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient.” Organic Process Research and Development, vol. 22, no. 6, May. 2018, pp. 736-740. https://doi.org/10.1021/acs.oprd.8b00076.