Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities
Publication type: Journal Article
Publication date: 2021-10-25
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The development of green Buchwald–Hartwig aminations has long been considered challenging, due to the high sensitivity of the reaction to the environment. Here we show that food-grade and waste vegetable oils, triglycerides originating from animals, and natural waxes can serve as excellent green solvents for Buchwald–Hartwig amination. We further demonstrate that amphiphiles and trace ingredients present in triglycerides as additives have a decisive effect on the yields of Buchwald–Hartwig aminations.
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11
Total citations:
11
Citations from 2024:
9
(81.82%)
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GOST
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Gevorgyan A., Hopmann K. H., Bayer A. Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities // Organometallics. 2021. Vol. 41. No. 14. pp. 1777-1785.
GOST all authors (up to 50)
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Gevorgyan A., Hopmann K. H., Bayer A. Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities // Organometallics. 2021. Vol. 41. No. 14. pp. 1777-1785.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.1c00517
UR - https://doi.org/10.1021/acs.organomet.1c00517
TI - Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities
T2 - Organometallics
AU - Gevorgyan, Ashot
AU - Hopmann, Kathrin Helen
AU - Bayer, Annette
PY - 2021
DA - 2021/10/25
PB - American Chemical Society (ACS)
SP - 1777-1785
IS - 14
VL - 41
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2021_Gevorgyan,
author = {Ashot Gevorgyan and Kathrin Helen Hopmann and Annette Bayer},
title = {Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities},
journal = {Organometallics},
year = {2021},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.organomet.1c00517},
number = {14},
pages = {1777--1785},
doi = {10.1021/acs.organomet.1c00517}
}
Cite this
MLA
Copy
Gevorgyan, Ashot, et al. “Improved Buchwald–Hartwig Amination by the Use of Lipids and Lipid Impurities.” Organometallics, vol. 41, no. 14, Oct. 2021, pp. 1777-1785. https://doi.org/10.1021/acs.organomet.1c00517.