Quantitative Assessment of the Lewis Acidity of Silylium Ions
Publication type: Journal Article
Publication date: 2015-10-06
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The Lewis acidity of several aryl-substituted tetrylium ions was classified experimentally by applying the Gutmann–Beckett method and computationally by calculation of fluoride ion affinities (FIA) (tetrel elements = Si, Ge). According to these measures, tetrylium ions are significantly more Lewis acidic than boranes, and aryl-substituted silylium borates are among the strongest isolable Lewis acids. A fine-tuning of the Lewis acidity of silylium ions is possible by taking advantage of electronic and/or steric substituent effects.
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Metrics
110
Total citations:
110
Citations from 2025:
9
(8.18%)
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GOST
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Großekappenberg H. et al. Quantitative Assessment of the Lewis Acidity of Silylium Ions // Organometallics. 2015. Vol. 34. No. 20. pp. 4952-4958.
GOST all authors (up to 50)
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Großekappenberg H., Reißmann M., Schmidtmann M., Müller T. Quantitative Assessment of the Lewis Acidity of Silylium Ions // Organometallics. 2015. Vol. 34. No. 20. pp. 4952-4958.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.5b00556
UR - https://doi.org/10.1021/acs.organomet.5b00556
TI - Quantitative Assessment of the Lewis Acidity of Silylium Ions
T2 - Organometallics
AU - Großekappenberg, Henning
AU - Reißmann, Matti
AU - Schmidtmann, M.
AU - Müller, TJ
PY - 2015
DA - 2015/10/06
PB - American Chemical Society (ACS)
SP - 4952-4958
IS - 20
VL - 34
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Großekappenberg,
author = {Henning Großekappenberg and Matti Reißmann and M. Schmidtmann and TJ Müller},
title = {Quantitative Assessment of the Lewis Acidity of Silylium Ions},
journal = {Organometallics},
year = {2015},
volume = {34},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.organomet.5b00556},
number = {20},
pages = {4952--4958},
doi = {10.1021/acs.organomet.5b00556}
}
Cite this
MLA
Copy
Großekappenberg, Henning, et al. “Quantitative Assessment of the Lewis Acidity of Silylium Ions.” Organometallics, vol. 34, no. 20, Oct. 2015, pp. 4952-4958. https://doi.org/10.1021/acs.organomet.5b00556.