Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules
Kirill I Tugashov
1
,
Dmitry A Gribanyov
1
,
Fedor Dolgushin
1
,
Alexander F. Smol’yakov
1
,
A. S. Peregudov
1
,
Marija Kh Minacheva
1
,
Irina Vasiljevna Tikhonova
1
,
Vladimir B. Shur
1
Publication type: Journal Article
Publication date: 2016-05-25
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interaction of the three-mercury anticrown (o-C6F4Hg)3 (1) with [PPh4][BF4] in methanol at room temperature leads to fluoride anion transfer from BF4– to 1 with the formation of a fluoride complex, [PPh4]{[(o-C6F4Hg)3]2F}, having a double-decker sandwich structure. The fluoride ion in this unique adduct is disposed between the mutually parallel planes of the central nine-membered rings of the anticrown units and cooperatively coordinated by all six Hg sites. The iodide anion also forms a double-decker sandwich in the interaction with 1, but this sandwich, [PPh4]{[(o-C6F4Hg)3]2I}, has a wedge-shaped geometry. The reaction of 1 with [nBu4N]Cl in dibromomethane at −15 °C affords a complex, [nBu4N]{[(o-C6F4Hg)3]2Cl(CH2Br2)2}, containing one chloride anion and two coordinated CH2Br2 species per two molecules of 1. A similar bromide complex of 1, containing two coordinated CH2Br2 moieties, has also been synthesized and structurally characterized. Both compounds represent wedge-shaped double-decker sandwiche...
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Tugashov K. I. et al. Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules // Organometallics. 2016. Vol. 35. No. 13. pp. 2197-2206.
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Tugashov K. I., Gribanyov D. A., Dolgushin F., Smol’yakov A. F., Peregudov A. S., Minacheva M. Kh., Tikhonova I. V., Shur V. B. Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules // Organometallics. 2016. Vol. 35. No. 13. pp. 2197-2206.
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TY - JOUR
DO - 10.1021/acs.organomet.6b00231
UR - https://doi.org/10.1021/acs.organomet.6b00231
TI - Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules
T2 - Organometallics
AU - Tugashov, Kirill I
AU - Gribanyov, Dmitry A
AU - Dolgushin, Fedor
AU - Smol’yakov, Alexander F.
AU - Peregudov, A. S.
AU - Minacheva, Marija Kh
AU - Tikhonova, Irina Vasiljevna
AU - Shur, Vladimir B.
PY - 2016
DA - 2016/05/25
PB - American Chemical Society (ACS)
SP - 2197-2206
IS - 13
VL - 35
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2016_Tugashov,
author = {Kirill I Tugashov and Dmitry A Gribanyov and Fedor Dolgushin and Alexander F. Smol’yakov and A. S. Peregudov and Marija Kh Minacheva and Irina Vasiljevna Tikhonova and Vladimir B. Shur},
title = {Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules},
journal = {Organometallics},
year = {2016},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.organomet.6b00231},
number = {13},
pages = {2197--2206},
doi = {10.1021/acs.organomet.6b00231}
}
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MLA
Copy
Tugashov, Kirill I., et al. “Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules.” Organometallics, vol. 35, no. 13, May. 2016, pp. 2197-2206. https://doi.org/10.1021/acs.organomet.6b00231.
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