Open Access
Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives
Тип публикации: Journal Article
Дата публикации: 2016-12-20
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
PubMed ID:
28133409
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Several silatranyl -substituted oligosilanes were prepared starting from bis(trimethylsilyl)silatranylsilanide. Electrochemical and theoretical investigations of some oligosilanes revealed that electrooxidation occurs by formation of a short-lived cation radical. This species undergoes structural relaxation to form a pair of conformers, with endo and exo relationships with respect to the Si-N interaction. Reaction of a 1,4-disilatranyl-1,4-disilanide with 1,2-dichlorotetramethyldisilane gave a mixture of cis and trans diastereomers of a cyclohexasilane with the trans isomer showing a diminished Si-N distance.
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Aghazadeh Meshgi M. et al. Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives // Organometallics. 2016. Vol. 36. No. 2. pp. 342-351.
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Aghazadeh Meshgi M., Baumgartner J., Jouikov V., Marschner C. Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives // Organometallics. 2016. Vol. 36. No. 2. pp. 342-351.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.6b00786
UR - https://doi.org/10.1021/acs.organomet.6b00786
TI - Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives
T2 - Organometallics
AU - Aghazadeh Meshgi, Mohammad
AU - Baumgartner, Judith
AU - Jouikov, Viatcheslav
AU - Marschner, C.
PY - 2016
DA - 2016/12/20
PB - American Chemical Society (ACS)
SP - 342-351
IS - 2
VL - 36
PMID - 28133409
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (до 50 авторов)
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@article{2016_Aghazadeh Meshgi,
author = {Mohammad Aghazadeh Meshgi and Judith Baumgartner and Viatcheslav Jouikov and C. Marschner},
title = {Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives},
journal = {Organometallics},
year = {2016},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.organomet.6b00786},
number = {2},
pages = {342--351},
doi = {10.1021/acs.organomet.6b00786}
}
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MLA
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Aghazadeh Meshgi, Mohammad, et al. “Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives.” Organometallics, vol. 36, no. 2, Dec. 2016, pp. 342-351. https://doi.org/10.1021/acs.organomet.6b00786.