Open Access

Organometallics

, volume 36 , issue 2 , pages 342-351

Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives

Mohammad Aghazadeh Meshgi ¹

Judith Baumgartner ²

Viatcheslav Jouikov ³

C. Marschner ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, 8010 Graz, Austria |

Institut für Chemie, Universität Graz, Stremayrgasse 9, 8010 Graz, Austria |

UMR 6226, Chimie et Photonique Moléculaires, Université de Rennes 1, 35042 Rennes, France |

Publication type: Journal Article

Publication date: 2016-12-20

American Chemical Society (ACS)

Organometallics

scimago Q2

wos Q1

SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/acs.organomet.6b00786

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PubMed ID: 28133409

Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Several silatranyl -substituted oligosilanes were prepared starting from bis(trimethylsilyl)silatranylsilanide. Electrochemical and theoretical investigations of some oligosilanes revealed that electrooxidation occurs by formation of a short-lived cation radical. This species undergoes structural relaxation to form a pair of conformers, with endo and exo relationships with respect to the Si-N interaction. Reaction of a 1,4-disilatranyl-1,4-disilanide with 1,2-dichlorotetramethyldisilane gave a mixture of cis and trans diastereomers of a cyclohexasilane with the trans isomer showing a diminished Si-N distance.

Found

4 citations

Zaitsev Kirill

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DSc in Chemistry

101 publications, 1 307 citations, 73 reviews

h-index: 23

Lomonosov Moscow State University

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Organometallic Chemistry

Titanium

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Churakov Andrei

PhD in Chemistry

553 publications, 7 015 citations, 13 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

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Doronina Evgeniya

PhD in Chemistry

41 publications, 432 citations

h-index: 13

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

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Aghazadeh Meshgi M. et al. Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives // Organometallics. 2016. Vol. 36. No. 2. pp. 342-351.

GOST all authors (up to 50) Copy

Aghazadeh Meshgi M., Baumgartner J., Jouikov V., Marschner C. Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives // Organometallics. 2016. Vol. 36. No. 2. pp. 342-351.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.organomet.6b00786

UR - https://doi.org/10.1021/acs.organomet.6b00786

TI - Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives

T2 - Organometallics

AU - Aghazadeh Meshgi, Mohammad

AU - Baumgartner, Judith

AU - Jouikov, Viatcheslav

AU - Marschner, C.

PY - 2016

DA - 2016/12/20

PB - American Chemical Society (ACS)

SP - 342-351

IS - 2

VL - 36

PMID - 28133409

SN - 0276-7333

SN - 1520-6041

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Aghazadeh Meshgi,

author = {Mohammad Aghazadeh Meshgi and Judith Baumgartner and Viatcheslav Jouikov and C. Marschner},

title = {Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives},

journal = {Organometallics},

year = {2016},

volume = {36},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/acs.organomet.6b00786},

number = {2},

pages = {342--351},

doi = {10.1021/acs.organomet.6b00786}

}

MLA

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MLA Copy

Aghazadeh Meshgi, Mohammad, et al. “Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives.” Organometallics, vol. 36, no. 2, Dec. 2016, pp. 342-351. https://doi.org/10.1021/acs.organomet.6b00786.

Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q2

wos Q1

SJR

0.676

CiteScore

5.1

Impact factor

2.9

ISSN

02767333 (Print)

15206041 (Electronic)

Profiles

Christoph Marschner