Open Access
Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes
Publication type: Journal Article
Publication date: 2017-03-21
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
PubMed ID:
28413239
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Most known silatrane chemistry is concerned with examples where the attached silatrane substituent atom is that of an element more electronegative than silicon. The current study features silylated silatranes with a range of electropositive elements attached to the silyl group. The resulting compounds show different degrees of electron density on the silatrane-substituted silicon atom. This directly affects the Si-N interaction of the silatrane which can be monitored either by 29Si NMR spectroscopy or directly by single crystal XRD analysis of the Si-N distance. Within the sample of study the Si-N distance is increased from 2.153 to 3.13 Å. Moreover, the bis(trimethylsilyl)silatranylsilyl unit was studied as a substituent for disilylated germylene adducts.
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Metrics
27
Total citations:
27
Citations from 2025:
1
(3.7%)
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GOST
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Aghazadeh Meshgi M. et al. Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes // Organometallics. 2017. Vol. 36. No. 7. pp. 1365-1371.
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Aghazadeh Meshgi M., Zitz R., Walewska M., Baumgartner J., Marschner C. Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes // Organometallics. 2017. Vol. 36. No. 7. pp. 1365-1371.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.organomet.7b00084
UR - https://doi.org/10.1021/acs.organomet.7b00084
TI - Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes
T2 - Organometallics
AU - Aghazadeh Meshgi, Mohammad
AU - Zitz, Rainer
AU - Walewska, Małgorzata
AU - Baumgartner, Judith
AU - Marschner, C.
PY - 2017
DA - 2017/03/21
PB - American Chemical Society (ACS)
SP - 1365-1371
IS - 7
VL - 36
PMID - 28413239
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Aghazadeh Meshgi,
author = {Mohammad Aghazadeh Meshgi and Rainer Zitz and Małgorzata Walewska and Judith Baumgartner and C. Marschner},
title = {Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.organomet.7b00084},
number = {7},
pages = {1365--1371},
doi = {10.1021/acs.organomet.7b00084}
}
Cite this
MLA
Copy
Aghazadeh Meshgi, Mohammad, et al. “Tuning the Si–N Interaction in Metalated Oligosilanylsilatranes.” Organometallics, vol. 36, no. 7, Mar. 2017, pp. 1365-1371. https://doi.org/10.1021/acs.organomet.7b00084.
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