Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships
Publication type: Journal Article
Publication date: 2017-04-06
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Detailed kinetic studies of the reaction of a model Ni0 complex with a range of aryl electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre-equilibrium, followed by oxidative addition to produce either [NiIX(dppf)] (and biaryl) or [NiII(Ar)X(dppf)]; the ortho substituent of the aryl halide determines selectivity between these possibilities. A reactivity scale is presented in which a range of substrates is quantitatively ranked in order of the rate at which they undergo oxidative addition. The rate of oxidative addition is loosely correlated to conversion in prototypical cross-coupling reactions. Substrates that lead to NiI products in kinetic experiments produce more homocoupling products under catalytic conditions.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
5
10
15
20
25
|
|
|
ACS Catalysis
23 publications, 14.02%
|
|
|
Journal of the American Chemical Society
21 publications, 12.8%
|
|
|
Organometallics
16 publications, 9.76%
|
|
|
Angewandte Chemie - International Edition
12 publications, 7.32%
|
|
|
Angewandte Chemie
12 publications, 7.32%
|
|
|
Chemistry - A European Journal
9 publications, 5.49%
|
|
|
Journal of Organic Chemistry
6 publications, 3.66%
|
|
|
Organic Letters
4 publications, 2.44%
|
|
|
Chemical Communications
4 publications, 2.44%
|
|
|
Advanced Synthesis and Catalysis
3 publications, 1.83%
|
|
|
Chemical Reviews
3 publications, 1.83%
|
|
|
Catalysis Science and Technology
3 publications, 1.83%
|
|
|
Accounts of Chemical Research
2 publications, 1.22%
|
|
|
European Journal of Inorganic Chemistry
2 publications, 1.22%
|
|
|
European Journal of Organic Chemistry
2 publications, 1.22%
|
|
|
ChemCatChem
2 publications, 1.22%
|
|
|
Chemical Science
2 publications, 1.22%
|
|
|
Synlett
2 publications, 1.22%
|
|
|
Advances in Organometallic Chemistry
2 publications, 1.22%
|
|
|
Journal of Chemical Sciences
1 publication, 0.61%
|
|
|
Communications Chemistry
1 publication, 0.61%
|
|
|
Molecular Catalysis
1 publication, 0.61%
|
|
|
Applied Surface Science
1 publication, 0.61%
|
|
|
Nature Communications
1 publication, 0.61%
|
|
|
Inorganica Chimica Acta
1 publication, 0.61%
|
|
|
Journal of Organometallic Chemistry
1 publication, 0.61%
|
|
|
Tetrahedron
1 publication, 0.61%
|
|
|
ChemPhotoChem
1 publication, 0.61%
|
|
|
Chemical Record
1 publication, 0.61%
|
|
|
5
10
15
20
25
|
Publishers
|
10
20
30
40
50
60
70
80
|
|
|
American Chemical Society (ACS)
77 publications, 46.95%
|
|
|
Wiley
49 publications, 29.88%
|
|
|
Elsevier
15 publications, 9.15%
|
|
|
Royal Society of Chemistry (RSC)
10 publications, 6.1%
|
|
|
Springer Nature
6 publications, 3.66%
|
|
|
Georg Thieme Verlag KG
3 publications, 1.83%
|
|
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.61%
|
|
|
Oxford University Press
1 publication, 0.61%
|
|
|
Japan Society of Coordination Chemistry
1 publication, 0.61%
|
|
|
10
20
30
40
50
60
70
80
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
166
Total citations:
166
Citations from 2024:
34
(20%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bajo S. et al. Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships // Organometallics. 2017. Vol. 36. No. 8. pp. 1662-1672.
GOST all authors (up to 50)
Copy
Bajo S., Laidlaw G., Kennedy M. R., Sproules S., Nelson D. J. Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships // Organometallics. 2017. Vol. 36. No. 8. pp. 1662-1672.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.organomet.7b00208
UR - https://doi.org/10.1021/acs.organomet.7b00208
TI - Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships
T2 - Organometallics
AU - Bajo, Sonia
AU - Laidlaw, Gillian
AU - Kennedy, M R
AU - Sproules, Stephen
AU - Nelson, D J
PY - 2017
DA - 2017/04/06
PB - American Chemical Society (ACS)
SP - 1662-1672
IS - 8
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Bajo,
author = {Sonia Bajo and Gillian Laidlaw and M R Kennedy and Stephen Sproules and D J Nelson},
title = {Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.organomet.7b00208},
number = {8},
pages = {1662--1672},
doi = {10.1021/acs.organomet.7b00208}
}
Cite this
MLA
Copy
Bajo, Sonia, et al. “Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships.” Organometallics, vol. 36, no. 8, Apr. 2017, pp. 1662-1672. https://doi.org/10.1021/acs.organomet.7b00208.