Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships
Тип публикации: Journal Article
Дата публикации: 2017-04-06
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Detailed kinetic studies of the reaction of a model Ni0 complex with a range of aryl electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre-equilibrium, followed by oxidative addition to produce either [NiIX(dppf)] (and biaryl) or [NiII(Ar)X(dppf)]; the ortho substituent of the aryl halide determines selectivity between these possibilities. A reactivity scale is presented in which a range of substrates is quantitatively ranked in order of the rate at which they undergo oxidative addition. The rate of oxidative addition is loosely correlated to conversion in prototypical cross-coupling reactions. Substrates that lead to NiI products in kinetic experiments produce more homocoupling products under catalytic conditions.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
5
10
15
20
25
|
|
|
ACS Catalysis
24 публикации, 14.04%
|
|
|
Journal of the American Chemical Society
22 публикации, 12.87%
|
|
|
Organometallics
16 публикаций, 9.36%
|
|
|
Angewandte Chemie - International Edition
13 публикаций, 7.6%
|
|
|
Angewandte Chemie
13 публикаций, 7.6%
|
|
|
Chemistry - A European Journal
9 публикаций, 5.26%
|
|
|
Journal of Organic Chemistry
6 публикаций, 3.51%
|
|
|
Organic Letters
4 публикации, 2.34%
|
|
|
Chemical Communications
4 публикации, 2.34%
|
|
|
Accounts of Chemical Research
3 публикации, 1.75%
|
|
|
Advanced Synthesis and Catalysis
3 публикации, 1.75%
|
|
|
Chemical Reviews
3 публикации, 1.75%
|
|
|
Catalysis Science and Technology
3 публикации, 1.75%
|
|
|
European Journal of Inorganic Chemistry
2 публикации, 1.17%
|
|
|
European Journal of Organic Chemistry
2 публикации, 1.17%
|
|
|
ChemCatChem
2 публикации, 1.17%
|
|
|
Chemical Science
2 публикации, 1.17%
|
|
|
Synlett
2 публикации, 1.17%
|
|
|
Advances in Organometallic Chemistry
2 публикации, 1.17%
|
|
|
Journal of Chemical Sciences
1 публикация, 0.58%
|
|
|
Communications Chemistry
1 публикация, 0.58%
|
|
|
Molecular Catalysis
1 публикация, 0.58%
|
|
|
Applied Surface Science
1 публикация, 0.58%
|
|
|
Nature Communications
1 публикация, 0.58%
|
|
|
Inorganica Chimica Acta
1 публикация, 0.58%
|
|
|
Journal of Organometallic Chemistry
1 публикация, 0.58%
|
|
|
Tetrahedron
1 публикация, 0.58%
|
|
|
ChemPhotoChem
1 публикация, 0.58%
|
|
|
Chemical Record
1 публикация, 0.58%
|
|
|
5
10
15
20
25
|
Издатели
|
10
20
30
40
50
60
70
80
|
|
|
American Chemical Society (ACS)
80 публикаций, 46.78%
|
|
|
Wiley
52 публикации, 30.41%
|
|
|
Elsevier
15 публикаций, 8.77%
|
|
|
Royal Society of Chemistry (RSC)
10 публикаций, 5.85%
|
|
|
Springer Nature
7 публикаций, 4.09%
|
|
|
Georg Thieme Verlag KG
3 публикации, 1.75%
|
|
|
American Association for the Advancement of Science (AAAS)
1 публикация, 0.58%
|
|
|
Oxford University Press
1 публикация, 0.58%
|
|
|
Japan Society of Coordination Chemistry
1 публикация, 0.58%
|
|
|
10
20
30
40
50
60
70
80
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
171
Всего цитирований:
171
Цитирований c 2025:
18
(10.52%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Bajo S. et al. Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships // Organometallics. 2017. Vol. 36. No. 8. pp. 1662-1672.
ГОСТ со всеми авторами (до 50)
Скопировать
Bajo S., Laidlaw G., Kennedy M. R., Sproules S., Nelson D. J. Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships // Organometallics. 2017. Vol. 36. No. 8. pp. 1662-1672.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/acs.organomet.7b00208
UR - https://doi.org/10.1021/acs.organomet.7b00208
TI - Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships
T2 - Organometallics
AU - Bajo, Sonia
AU - Laidlaw, Gillian
AU - Kennedy, M R
AU - Sproules, Stephen
AU - Nelson, D J
PY - 2017
DA - 2017/04/06
PB - American Chemical Society (ACS)
SP - 1662-1672
IS - 8
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2017_Bajo,
author = {Sonia Bajo and Gillian Laidlaw and M R Kennedy and Stephen Sproules and D J Nelson},
title = {Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.organomet.7b00208},
number = {8},
pages = {1662--1672},
doi = {10.1021/acs.organomet.7b00208}
}
Цитировать
MLA
Скопировать
Bajo, Sonia, et al. “Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships.” Organometallics, vol. 36, no. 8, Apr. 2017, pp. 1662-1672. https://doi.org/10.1021/acs.organomet.7b00208.