N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes
Publication type: Journal Article
Publication date: 2019-03-11
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Recent years have witnessed a significant growth in the area of low-valent main-group compounds due to their potential to activate small molecules. However, there is a paucity of examples of low-valent main-group compounds being used as single-site catalysts for organic transformations. This study represents the hydroboration and cyanosilylation reactions of a range of aldehydes by a benzannulated heavier N-heterocyclic germylene (1) and stannylene (2) under mild conditions. A wide variety of substrate scope was studied. The mechanistic pathway of the cyanosilylation reaction is initiated through the coordination of TMSCN with the catalyst followed by the attack of aldehydes. Conversely, hydroboration proceeds via formation of a donor–acceptor adduct between HBpin and the catalyst. Experimental and theoretical studies were performed to establish the mechanism.
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78
Total citations:
78
Citations from 2025:
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(15.38%)
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GOST
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Dasgupta R. et al. N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes // Organometallics. 2019. Vol. 38. No. 7. pp. 1429-1435.
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Dasgupta R., Das S., Hiwase S., Pati S. K., Khan S. N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes // Organometallics. 2019. Vol. 38. No. 7. pp. 1429-1435.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.8b00673
UR - https://doi.org/10.1021/acs.organomet.8b00673
TI - N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes
T2 - Organometallics
AU - Dasgupta, Rajarshi
AU - Das, Shubhajit
AU - Hiwase, Shweta
AU - Pati, Swapan Kumar
AU - Khan, Shabana
PY - 2019
DA - 2019/03/11
PB - American Chemical Society (ACS)
SP - 1429-1435
IS - 7
VL - 38
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2019_Dasgupta,
author = {Rajarshi Dasgupta and Shubhajit Das and Shweta Hiwase and Swapan Kumar Pati and Shabana Khan},
title = {N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes},
journal = {Organometallics},
year = {2019},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.organomet.8b00673},
number = {7},
pages = {1429--1435},
doi = {10.1021/acs.organomet.8b00673}
}
Cite this
MLA
Copy
Dasgupta, Rajarshi, et al. “N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes.” Organometallics, vol. 38, no. 7, Mar. 2019, pp. 1429-1435. https://doi.org/10.1021/acs.organomet.8b00673.