Organometallics, volume 38, issue 2, pages 205-209
Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2
Publication type: Journal Article
Publication date: 2018-12-24
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
By using a zerovalent, electron-rich ruthenium complex bearing a tetradentate phosphine ligand, a five-membered ruthenalactone was generated by oxidative cyclization of ethylene and CO2. This ruthenalactone underwent thermal, reversible β-H elimination to afford an acrylato(hydrido)ruthenium(II) complex, which liberated acrylate salt on treatment with a base. The reaction was successfully applied to the first ruthenium-catalyzed synthesis of an acrylate salt from ethylene and CO2. This study demonstrated the feasibility of the electron-rich ruthenium(0) complex as a catalyst in CO2-fixation chemistry.
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Ito T., Takahashi K., Iwasawa N. Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2 // Organometallics. 2018. Vol. 38. No. 2. pp. 205-209.
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Ito T., Takahashi K., Iwasawa N. Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2 // Organometallics. 2018. Vol. 38. No. 2. pp. 205-209.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.organomet.8b00789
UR - https://doi.org/10.1021/acs.organomet.8b00789
TI - Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2
T2 - Organometallics
AU - Ito, Tatsuyoshi
AU - Takahashi, Kohei
AU - Iwasawa, N.
PY - 2018
DA - 2018/12/24
PB - American Chemical Society (ACS)
SP - 205-209
IS - 2
VL - 38
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex
Copy
@article{2018_Ito,
author = {Tatsuyoshi Ito and Kohei Takahashi and N. Iwasawa},
title = {Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2},
journal = {Organometallics},
year = {2018},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.organomet.8b00789},
number = {2},
pages = {205--209},
doi = {10.1021/acs.organomet.8b00789}
}
Cite this
MLA
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Ito, Tatsuyoshi, et al. “Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2.” Organometallics, vol. 38, no. 2, Dec. 2018, pp. 205-209. https://doi.org/10.1021/acs.organomet.8b00789.